volume 282 pages 121125

Stable zinc metal-organic framework materials constructed by fluorenone carboxylate ligand: Multifunction detection and photocatalysis property

Publication typeJournal Article
Publication date2020-02-01
scimago Q2
wos Q1
SJR0.629
CiteScore6.8
Impact factor3.5
ISSN00224596, 1095726X
Materials Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Inorganic Chemistry
Physical and Theoretical Chemistry
Condensed Matter Physics
Abstract
In this paper, we synthesized a zinc metal-organic framework material (Zn-MOF) based on fluorenone carboxylate ligand and studied the application of Zn-MOF in the fields of fluorescent detection and photocatalysis degradation. The experiment results show that it is a fluorescent probe that can quickly recognize organic solvent nitrobenzene (NB) from other solvents. The detection limit is 2.9 ​μM, and Ksv (quenching efficiency) is 3.547 ​× ​103 ​M−1. In particular, Zn-MOF can identify nitrobenzene derivatives, such as nitrophenol and nitrotoluene, and the quenching efficiency can reach 16.54% and 92.64%, respectively. Moreover, Zn-MOF can be used to detect metal ions and has high selectivity for Al3+ and Fe3+ ions. Competitive experiments show that other metal ions will not interfere with the detection. In addition, Zn-MOF can also be used as photocatalytic degradation of Rhodamine B (RhB), and the photodegradation efficiency of RhB can reach 85% within 3 ​h.
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Cheng J. et al. Stable zinc metal-organic framework materials constructed by fluorenone carboxylate ligand: Multifunction detection and photocatalysis property // Journal of Solid State Chemistry. 2020. Vol. 282. p. 121125.
GOST all authors (up to 50) Copy
Cheng J., Hu T., Li W., Chang Z., Sun C. Stable zinc metal-organic framework materials constructed by fluorenone carboxylate ligand: Multifunction detection and photocatalysis property // Journal of Solid State Chemistry. 2020. Vol. 282. p. 121125.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.jssc.2019.121125
UR - https://doi.org/10.1016/j.jssc.2019.121125
TI - Stable zinc metal-organic framework materials constructed by fluorenone carboxylate ligand: Multifunction detection and photocatalysis property
T2 - Journal of Solid State Chemistry
AU - Cheng, Jiapeng
AU - Hu, Tao
AU - Li, Wenjun
AU - Chang, Zhidong
AU - Sun, Changyan
PY - 2020
DA - 2020/02/01
PB - Elsevier
SP - 121125
VL - 282
SN - 0022-4596
SN - 1095-726X
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Cheng,
author = {Jiapeng Cheng and Tao Hu and Wenjun Li and Zhidong Chang and Changyan Sun},
title = {Stable zinc metal-organic framework materials constructed by fluorenone carboxylate ligand: Multifunction detection and photocatalysis property},
journal = {Journal of Solid State Chemistry},
year = {2020},
volume = {282},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.jssc.2019.121125},
pages = {121125},
doi = {10.1016/j.jssc.2019.121125}
}