Journal of the Taiwan Institute of Chemical Engineers, volume 144, pages 104681
Atomic layer deposition of ZnO on Li1.3Al0.3Ti1.7(PO4)3 enables its application in all solid-state lithium batteries
Chengfeng Li
1
,
R. Muruganantham
1
,
Wei-Chun Hsu
2
,
Martin Ihrig
3
,
Chien-Te Hsieh
4, 5
,
Chih Chieh Wang
2
,
Wei-Ren Liu
1
5
Department of Mechanical, Aerospace, and Biomedical Engineering, University of Tennessee, Knoxville, TN, 37996, United States
|
Publication type: Journal Article
Publication date: 2023-03-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 5.7
ISSN: 18761070
General Chemistry
General Chemical Engineering
Abstract
All-solid-state Li batteries (ASSLBs) are emerging as potential electrochemical energy storage devices for next-generation large-scale electrical power systems. In particular, Li1.3Al0.3Ti1.7(PO4)3 (LATP) is an efficient cost-effective solid-state electrolyte with high ionic conductivity for high energy density and safety ASSLBs. Since LATP is unstable verus metallic Li. Therefore, the application of Li-based all-solid-state batteries is practically limited. As a possible solution to overcome the LATP instability, the interface was modified by adding a 5 nm thin ZnO layer on LATP using the atomic layer deposition (ALD) technique. The ZnO layer reduces the observed overpotential in a Li|ZnO@LATP|Li symmetric cell compared to an unmodified LATP-based cell. In contrast to the unmodified LATP-based Li cells, the ZnO-modified symmetric LATP-based Li cells show stable cycling for more than 500 h without a short circuit. The full-cell configuration of the LiFePO4|ZnO@LATP|Li system showed a reversible capacity of 156 mAh/g over 50 cycles and exposed good capacity retention (98.79% after 50 cycles) during the cycling test. The results indicate that ZnO coating by ALD on LATP could overcome the stability issues of pristine LATP versus metallic Li. Therefore, this work will lead to prove the simple manner of interfacial modification and improvement of electrochemical performance of inorganic oxide based solid electrolytes for all-solid-state lithium battery applications.
Top-30
Citations by journals
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3 publications, 21.43%
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2 publications, 14.29%
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1 publication, 7.14%
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Materials Chemistry Frontiers
1 publication, 7.14%
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1 publication, 7.14%
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1 publication, 7.14%
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1 publication, 7.14%
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1 publication, 7.14%
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1 publication, 7.14%
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1 publication, 7.14%
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Russian Chemical Reviews
1 publication, 7.14%
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1
2
3
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Citations by publishers
1
2
3
4
5
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Elsevier
5 publications, 35.71%
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American Chemical Society (ACS)
3 publications, 21.43%
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The Electrochemical Society
2 publications, 14.29%
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 7.14%
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Royal Society of Chemistry (RSC)
1 publication, 7.14%
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Wiley
1 publication, 7.14%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 7.14%
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1
2
3
4
5
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Li C. et al. Atomic layer deposition of ZnO on Li1.3Al0.3Ti1.7(PO4)3 enables its application in all solid-state lithium batteries // Journal of the Taiwan Institute of Chemical Engineers. 2023. Vol. 144. p. 104681.
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Li C., Muruganantham R., Hsu W., Ihrig M., Hsieh C., Wang C. C., Liu W. Atomic layer deposition of ZnO on Li1.3Al0.3Ti1.7(PO4)3 enables its application in all solid-state lithium batteries // Journal of the Taiwan Institute of Chemical Engineers. 2023. Vol. 144. p. 104681.
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TY - JOUR
DO - 10.1016/j.jtice.2023.104681
UR - https://doi.org/10.1016/j.jtice.2023.104681
TI - Atomic layer deposition of ZnO on Li1.3Al0.3Ti1.7(PO4)3 enables its application in all solid-state lithium batteries
T2 - Journal of the Taiwan Institute of Chemical Engineers
AU - Li, Chengfeng
AU - Muruganantham, R.
AU - Hsu, Wei-Chun
AU - Ihrig, Martin
AU - Hsieh, Chien-Te
AU - Wang, Chih Chieh
AU - Liu, Wei-Ren
PY - 2023
DA - 2023/03/01 00:00:00
PB - Taiwan Institute of Chemical Engineers
SP - 104681
VL - 144
SN - 1876-1070
ER -
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@article{2023_Li,
author = {Chengfeng Li and R. Muruganantham and Wei-Chun Hsu and Martin Ihrig and Chien-Te Hsieh and Chih Chieh Wang and Wei-Ren Liu},
title = {Atomic layer deposition of ZnO on Li1.3Al0.3Ti1.7(PO4)3 enables its application in all solid-state lithium batteries},
journal = {Journal of the Taiwan Institute of Chemical Engineers},
year = {2023},
volume = {144},
publisher = {Taiwan Institute of Chemical Engineers},
month = {mar},
url = {https://doi.org/10.1016/j.jtice.2023.104681},
pages = {104681},
doi = {10.1016/j.jtice.2023.104681}
}
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