Journal of the Taiwan Institute of Chemical Engineers, volume 144, pages 104681

Atomic layer deposition of ZnO on Li1.3Al0.3Ti1.7(PO4)3 enables its application in all solid-state lithium batteries

Chengfeng Li 1
R. Muruganantham 1
Wei-Chun Hsu 2
Martin Ihrig 3
Chien-Te Hsieh 4, 5
Chih Chieh Wang 2
Wei-Ren Liu 1
Publication typeJournal Article
Publication date2023-03-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor5.7
ISSN18761070
General Chemistry
General Chemical Engineering
Abstract
All-solid-state Li batteries (ASSLBs) are emerging as potential electrochemical energy storage devices for next-generation large-scale electrical power systems. In particular, Li1.3Al0.3Ti1.7(PO4)3 (LATP) is an efficient cost-effective solid-state electrolyte with high ionic conductivity for high energy density and safety ASSLBs. Since LATP is unstable verus metallic Li. Therefore, the application of Li-based all-solid-state batteries is practically limited. As a possible solution to overcome the LATP instability, the interface was modified by adding a 5 nm thin ZnO layer on LATP using the atomic layer deposition (ALD) technique. The ZnO layer reduces the observed overpotential in a Li|ZnO@LATP|Li symmetric cell compared to an unmodified LATP-based cell. In contrast to the unmodified LATP-based Li cells, the ZnO-modified symmetric LATP-based Li cells show stable cycling for more than 500 h without a short circuit. The full-cell configuration of the LiFePO4|ZnO@LATP|Li system showed a reversible capacity of 156 mAh/g over 50 cycles and exposed good capacity retention (98.79% after 50 cycles) during the cycling test. The results indicate that ZnO coating by ALD on LATP could overcome the stability issues of pristine LATP versus metallic Li. Therefore, this work will lead to prove the simple manner of interfacial modification and improvement of electrochemical performance of inorganic oxide based solid electrolytes for all-solid-state lithium battery applications.

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Li C. et al. Atomic layer deposition of ZnO on Li1.3Al0.3Ti1.7(PO4)3 enables its application in all solid-state lithium batteries // Journal of the Taiwan Institute of Chemical Engineers. 2023. Vol. 144. p. 104681.
GOST all authors (up to 50) Copy
Li C., Muruganantham R., Hsu W., Ihrig M., Hsieh C., Wang C. C., Liu W. Atomic layer deposition of ZnO on Li1.3Al0.3Ti1.7(PO4)3 enables its application in all solid-state lithium batteries // Journal of the Taiwan Institute of Chemical Engineers. 2023. Vol. 144. p. 104681.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.jtice.2023.104681
UR - https://doi.org/10.1016/j.jtice.2023.104681
TI - Atomic layer deposition of ZnO on Li1.3Al0.3Ti1.7(PO4)3 enables its application in all solid-state lithium batteries
T2 - Journal of the Taiwan Institute of Chemical Engineers
AU - Li, Chengfeng
AU - Muruganantham, R.
AU - Hsu, Wei-Chun
AU - Ihrig, Martin
AU - Hsieh, Chien-Te
AU - Wang, Chih Chieh
AU - Liu, Wei-Ren
PY - 2023
DA - 2023/03/01 00:00:00
PB - Taiwan Institute of Chemical Engineers
SP - 104681
VL - 144
SN - 1876-1070
ER -
BibTex
Cite this
BibTex Copy
@article{2023_Li,
author = {Chengfeng Li and R. Muruganantham and Wei-Chun Hsu and Martin Ihrig and Chien-Te Hsieh and Chih Chieh Wang and Wei-Ren Liu},
title = {Atomic layer deposition of ZnO on Li1.3Al0.3Ti1.7(PO4)3 enables its application in all solid-state lithium batteries},
journal = {Journal of the Taiwan Institute of Chemical Engineers},
year = {2023},
volume = {144},
publisher = {Taiwan Institute of Chemical Engineers},
month = {mar},
url = {https://doi.org/10.1016/j.jtice.2023.104681},
pages = {104681},
doi = {10.1016/j.jtice.2023.104681}
}
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