volume 43 issue 2 pages 377-383

Phase transitions and ionic mobility in hydrogen zirconium phosphates with the NASICON structure, H1±XZr2−XMX(PO4)3·H2O, M=Nb, Y

Publication typeJournal Article
Publication date2008-02-01
scimago Q1
wos Q2
SJR0.943
CiteScore9.9
Impact factor5.7
ISSN00255408, 18734227
Condensed Matter Physics
General Materials Science
Mechanical Engineering
Mechanics of Materials
Abstract
Phase transitions and the mobility of proton-containing groups in hydrogen zirconium phosphate HZr2(PO4)3·nH2O with the NASICON structure were studied by X-ray powder diffraction, 1H, 31P NMR, IR spectroscopy and TG analysis. Heating HZr2(PO4)3·H2O above 420 K results in dehydration and in a rhombohedral–triclinic phase transition. Continued heating to about 490 K results in the thermal activation of cation disordering and phase transition of HZr2(PO4)3 from triclinic to rhombohedral phase. Parameter “a” of HZr2(PO4)3 lattice decreases during the heating. It is shown that oxonium ions in HZr2(PO4)3·H2O are characterized by high rotation and translation mobility. Rotation mobility of oxonium ions can be increased by the substitution of zirconium by yttrium or niobium.
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Stenina I. A. et al. Phase transitions and ionic mobility in hydrogen zirconium phosphates with the NASICON structure, H1±XZr2−XMX(PO4)3·H2O, M=Nb, Y // Materials Research Bulletin. 2008. Vol. 43. No. 2. pp. 377-383.
GOST all authors (up to 50) Copy
Stenina I. A., Kislitsyn M. N., Ghuravlev N. A., Yaroslavtsev A. B. Phase transitions and ionic mobility in hydrogen zirconium phosphates with the NASICON structure, H1±XZr2−XMX(PO4)3·H2O, M=Nb, Y // Materials Research Bulletin. 2008. Vol. 43. No. 2. pp. 377-383.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.materresbull.2007.03.003
UR - https://linkinghub.elsevier.com/retrieve/pii/S0025540807001092
TI - Phase transitions and ionic mobility in hydrogen zirconium phosphates with the NASICON structure, H1±XZr2−XMX(PO4)3·H2O, M=Nb, Y
T2 - Materials Research Bulletin
AU - Stenina, Irina A
AU - Kislitsyn, M N
AU - Ghuravlev, N A
AU - Yaroslavtsev, A. B.
PY - 2008
DA - 2008/02/01
PB - Elsevier
SP - 377-383
IS - 2
VL - 43
SN - 0025-5408
SN - 1873-4227
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2008_Stenina,
author = {Irina A Stenina and M N Kislitsyn and N A Ghuravlev and A. B. Yaroslavtsev},
title = {Phase transitions and ionic mobility in hydrogen zirconium phosphates with the NASICON structure, H1±XZr2−XMX(PO4)3·H2O, M=Nb, Y},
journal = {Materials Research Bulletin},
year = {2008},
volume = {43},
publisher = {Elsevier},
month = {feb},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0025540807001092},
number = {2},
pages = {377--383},
doi = {10.1016/j.materresbull.2007.03.003}
}
MLA
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Stenina, Irina A., et al. “Phase transitions and ionic mobility in hydrogen zirconium phosphates with the NASICON structure, H1±XZr2−XMX(PO4)3·H2O, M=Nb, Y.” Materials Research Bulletin, vol. 43, no. 2, Feb. 2008, pp. 377-383. https://linkinghub.elsevier.com/retrieve/pii/S0025540807001092.