volume 62 issue 16 pages 2461-2464

Mechanochemical synthesis and characterization of TiB2 and VB2 nanopowders

Ji Gang Kim 1, 2
Jae-Hyeok Shim 3
Jae-Pyoung Ahn 4
Young Kuk Cho 3
Jae-Hun Kim 3
Kyu Hwan Oh 5
Publication typeJournal Article
Publication date2008-06-01
scimago Q2
wos Q3
SJR0.591
CiteScore5.4
Impact factor2.7
ISSN0167577X, 18734979
Condensed Matter Physics
General Materials Science
Mechanical Engineering
Mechanics of Materials
Abstract
A novel method for the synthesis of transition-metal boride nanopowder has been developed using a mechanochemical reaction between LiBH 4 , LiH and transition-metal chloride (TiCl 3 and VCl 3 ) by high energy ball milling. This method successfully produces TiB 2 and VB 2 particles dispersed within a soluble LiCl matrix. Subsequent washing with distilled water, ethanol and acetone to remove the LiCl matrix phase yields TiB 2 and VB 2 nanopowders of 15–60 nm particle size. From the X-ray diffraction patterns and high resolution transmission electron microscopy image, it is found that each particle is polycrystalline consisting of 3–5 nm crystallites. Neither particle nor crystallite size are increased significantly after heating at 680 °C.
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GOST |
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GOST Copy
Kim J. G. et al. Mechanochemical synthesis and characterization of TiB2 and VB2 nanopowders // Materials Letters. 2008. Vol. 62. No. 16. pp. 2461-2464.
GOST all authors (up to 50) Copy
Kim J. G., Shim J., Ahn J., Cho Y. K., Kim J., Oh K. H. Mechanochemical synthesis and characterization of TiB2 and VB2 nanopowders // Materials Letters. 2008. Vol. 62. No. 16. pp. 2461-2464.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.matlet.2007.12.022
UR - https://doi.org/10.1016/j.matlet.2007.12.022
TI - Mechanochemical synthesis and characterization of TiB2 and VB2 nanopowders
T2 - Materials Letters
AU - Kim, Ji Gang
AU - Shim, Jae-Hyeok
AU - Ahn, Jae-Pyoung
AU - Cho, Young Kuk
AU - Kim, Jae-Hun
AU - Oh, Kyu Hwan
PY - 2008
DA - 2008/06/01
PB - Elsevier
SP - 2461-2464
IS - 16
VL - 62
SN - 0167-577X
SN - 1873-4979
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2008_Kim,
author = {Ji Gang Kim and Jae-Hyeok Shim and Jae-Pyoung Ahn and Young Kuk Cho and Jae-Hun Kim and Kyu Hwan Oh},
title = {Mechanochemical synthesis and characterization of TiB2 and VB2 nanopowders},
journal = {Materials Letters},
year = {2008},
volume = {62},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/j.matlet.2007.12.022},
number = {16},
pages = {2461--2464},
doi = {10.1016/j.matlet.2007.12.022}
}
MLA
Cite this
MLA Copy
Kim, Ji Gang, et al. “Mechanochemical synthesis and characterization of TiB2 and VB2 nanopowders.” Materials Letters, vol. 62, no. 16, Jun. 2008, pp. 2461-2464. https://doi.org/10.1016/j.matlet.2007.12.022.