Novel configuration of heat-resistant gel polymer electrolyte with electrospun poly (vinylidene fluoride-co-hexafluoropropylene) and poly-m-phenyleneisophthalamide composite separator for high-safety lithium-ion battery
Publication type: Journal Article
Publication date: 2019-02-01
scimago Q2
wos Q3
SJR: 0.591
CiteScore: 5.4
Impact factor: 2.7
ISSN: 0167577X, 18734979
Condensed Matter Physics
General Materials Science
Mechanical Engineering
Mechanics of Materials
Abstract
In this work, a novel nanofiber composite membrane constituting poly (vinylidene fluoride-co-hexafluoropropylene)/poly-m-phenyleneiso-phthalamide (PVDF-HFP/PMIA) was successfully fabricated through one-step electrospinning technique. The PVDF-HFP/PMIA nanofibers possessed low average diameter and uniform diameter distribution, which were able to be acted as matrix for gel polymer electrolyte. Significantly, the presence of PVDF-HFP endowed PMIA membrane with considerable high electrolyte uptake and porosity, eminent mechanical strength and remarkable thermal shrinkage resistance. Compared with pure PMIA and polyethylene separators, the PVDF-HFP/PMIA separator obtained higher ionic conductivity, lower interfacial resistance and more stable electrochemical window. The Li/LiCoO2 battery with the prepared separator reflected admirable cycle stability with outstanding first discharge capacity up to 153.8 mAh g−1 at 0.5C rate and superior capacity retention of 88.75% after 100 cycles.
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Total citations:
40
Citations from 2025:
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(7.5%)
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GOST
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Zhao H. et al. Novel configuration of heat-resistant gel polymer electrolyte with electrospun poly (vinylidene fluoride-co-hexafluoropropylene) and poly-m-phenyleneisophthalamide composite separator for high-safety lithium-ion battery // Materials Letters. 2019. Vol. 236. pp. 101-105.
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Zhao H., Deng N., Ju J., Li Z., Kang W., Cheng B. Novel configuration of heat-resistant gel polymer electrolyte with electrospun poly (vinylidene fluoride-co-hexafluoropropylene) and poly-m-phenyleneisophthalamide composite separator for high-safety lithium-ion battery // Materials Letters. 2019. Vol. 236. pp. 101-105.
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TY - JOUR
DO - 10.1016/j.matlet.2018.10.067
UR - https://doi.org/10.1016/j.matlet.2018.10.067
TI - Novel configuration of heat-resistant gel polymer electrolyte with electrospun poly (vinylidene fluoride-co-hexafluoropropylene) and poly-m-phenyleneisophthalamide composite separator for high-safety lithium-ion battery
T2 - Materials Letters
AU - Zhao, Huijuan
AU - Deng, Nanping
AU - Ju, Jingge
AU - Li, Zongjie
AU - Kang, Weimin
AU - Cheng, Bowen
PY - 2019
DA - 2019/02/01
PB - Elsevier
SP - 101-105
VL - 236
SN - 0167-577X
SN - 1873-4979
ER -
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@article{2019_Zhao,
author = {Huijuan Zhao and Nanping Deng and Jingge Ju and Zongjie Li and Weimin Kang and Bowen Cheng},
title = {Novel configuration of heat-resistant gel polymer electrolyte with electrospun poly (vinylidene fluoride-co-hexafluoropropylene) and poly-m-phenyleneisophthalamide composite separator for high-safety lithium-ion battery},
journal = {Materials Letters},
year = {2019},
volume = {236},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.matlet.2018.10.067},
pages = {101--105},
doi = {10.1016/j.matlet.2018.10.067}
}