Materials Today, volume 64, pages 52-60

Achieving stable all-solid-state lithium-metal batteries by tuning the cathode-electrolyte interface and ionic/electronic transport within the cathode

Ruyi Fang ¹

Yijie Liu ¹

Y. Li ¹

Arumugam Manthiram ¹

John B. Goodenough ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Materials Science and Engineering Program and Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78712, USA |

Publication type: Journal Article

Publication date: 2023-04-01

Elsevier

Journal: Materials Today

Quartile SCImago

Quartile WOS

Impact factor: 24.2

ISSN: 13697021

DOI: 10.1016/j.mattod.2023.03.001

Copy DOI

Condensed Matter Physics

General Materials Science

Mechanical Engineering

Mechanics of Materials

Abstract

All-solid-state batteries with sulfide electrolytes and high-nickel layered oxide cathodes attract much interest due to their high specific energy. However, their cycling performance is primarily influenced by the interface between the sulfide electrolyte and the high-Ni layered oxide particles, which requires the use of composite cathodes with high ionic and electronic conductivities to achieve a kinetically stable interface inside the cathode. Here, we apply Ti2O3 particles to the high-Ni cathode LiNi0.8Co0.1Mn0.1O2 (NCM811), where Ti2O3 not only acts as an electronic conductor to provide a fast diffusion path for electrons in the composite cathode, but also absorbs the lattice oxygen released from NCM811 cathode during cycling, stabilizing the Li6PS5Cl/NCM811 interface and suppressing electrolyte oxidation. The as-modified cathode exhibits an initial specific capacity of 192 mAh g−1 and retains 166 mAh g−1 after 140 cycles at 0.1C rate with a good capacity retention of 86.5%. Furthermore, the composite cathode displays high rate capability even at 1C rate. By contrast, the unmodified Li6PS5Cl/NCM811 cathode shows poor cycling performance with only 130 mAh g−1 remaining after 130 cycles. This work provides a new direction for the design of cathodes for all-solid-state batteries that can deliver high specific energy with long cycle life.

By date By citations

Top-30

Citations by journals

	1 2 3
Advanced Functional Materials	Advanced Functional Materials, 3, 7.69% Advanced Functional Materials 3 publications, 7.69%
Progress in Materials Science	Progress in Materials Science, 2, 5.13% Progress in Materials Science 2 publications, 5.13%
Nano Letters	Nano Letters, 2, 5.13% Nano Letters 2 publications, 5.13%
ACS applied materials & interfaces	ACS applied materials & interfaces, 2, 5.13% ACS applied materials & interfaces 2 publications, 5.13%
Journal of Solid State Electrochemistry	Journal of Solid State Electrochemistry, 2, 5.13% Journal of Solid State Electrochemistry 2 publications, 5.13%
Small	Small, 2, 5.13% Small 2 publications, 5.13%
ChemSusChem	ChemSusChem, 2, 5.13% ChemSusChem 2 publications, 5.13%
Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 2, 5.13% Journal of Colloid and Interface Science 2 publications, 5.13%
Nano Energy	Nano Energy, 2, 5.13% Nano Energy 2 publications, 5.13%
Chemical Engineering Journal	Chemical Engineering Journal, 2, 5.13% Chemical Engineering Journal 2 publications, 5.13%
Materials Today Chemistry	Materials Today Chemistry, 1, 2.56% Materials Today Chemistry 1 publication, 2.56%
Nature Nanotechnology	Nature Nanotechnology, 1, 2.56% Nature Nanotechnology 1 publication, 2.56%
Energy Storage Materials	Energy Storage Materials, 1, 2.56% Energy Storage Materials 1 publication, 2.56%
Advanced Materials	Advanced Materials, 1, 2.56% Advanced Materials 1 publication, 2.56%
Advanced Powder Materials	Advanced Powder Materials, 1, 2.56% Advanced Powder Materials 1 publication, 2.56%
Carbon	Carbon, 1, 2.56% Carbon 1 publication, 2.56%
Materials Research Express	Materials Research Express, 1, 2.56% Materials Research Express 1 publication, 2.56%
Energy & Fuels	Energy & Fuels, 1, 2.56% Energy & Fuels 1 publication, 2.56%
ACS Applied Energy Materials	ACS Applied Energy Materials, 1, 2.56% ACS Applied Energy Materials 1 publication, 2.56%
ACS Applied Engineering Materials	ACS Applied Engineering Materials, 1, 2.56% ACS Applied Engineering Materials 1 publication, 2.56%
Analytical Letters	Analytical Letters, 1, 2.56% Analytical Letters 1 publication, 2.56%
ACS Omega	ACS Omega, 1, 2.56% ACS Omega 1 publication, 2.56%
ACS Nano	ACS Nano, 1, 2.56% ACS Nano 1 publication, 2.56%
Frontiers of Chemical Science and Engineering	Frontiers of Chemical Science and Engineering, 1, 2.56% Frontiers of Chemical Science and Engineering 1 publication, 2.56%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 2.56% Russian Chemical Reviews 1 publication, 2.56%
Advanced Energy Materials	Advanced Energy Materials, 1, 2.56% Advanced Energy Materials 1 publication, 2.56%
Journal of Power Sources	Journal of Power Sources, 1, 2.56% Journal of Power Sources 1 publication, 2.56%
ChemistrySelect	ChemistrySelect, 1, 2.56% ChemistrySelect 1 publication, 2.56%
	1 2 3

Citations by publishers

	2 4 6 8 10 12 14
Elsevier	Elsevier, 13, 33.33% Elsevier 13 publications, 33.33%
Wiley	Wiley, 10, 25.64% Wiley 10 publications, 25.64%
American Chemical Society (ACS)	American Chemical Society (ACS), 9, 23.08% American Chemical Society (ACS) 9 publications, 23.08%
Springer Nature	Springer Nature, 4, 10.26% Springer Nature 4 publications, 10.26%
IOP Publishing	IOP Publishing, 1, 2.56% IOP Publishing 1 publication, 2.56%
Taylor & Francis	Taylor & Francis, 1, 2.56% Taylor & Francis 1 publication, 2.56%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 2.56% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 2.56%
	2 4 6 8 10 12 14

We do not take into account publications without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2023,2024],"ids":[0,0],"codes":[0,0],"imageUrls":["",""],"datasets":[{"label":"Citations number","data":[8,31],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":["20.51","79.49"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Advanced Functional Materials","Progress in Materials Science","Nano Letters","ACS applied materials & interfaces","Journal of Solid State Electrochemistry","Small","ChemSusChem","Journal of Colloid and Interface Science","Nano Energy","Chemical Engineering Journal","Materials Today Chemistry","Nature Nanotechnology","Energy Storage Materials","Advanced Materials","Advanced Powder Materials","Carbon","Materials Research Express","Energy & Fuels","ACS Applied Energy Materials","ACS Applied Engineering Materials","Analytical Letters","ACS Omega","ACS Nano","Frontiers of Chemical Science and Engineering","Russian Chemical Reviews","Advanced Energy Materials","Journal of Power Sources","ChemistrySelect"],"ids":[7715,21250,10312,1458,10804,9872,6896,24202,23236,16275,1350,337,3858,25159,30816,37,3993,10347,6419,28553,16571,18901,8724,8883,23802,22475,14844,8021],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/fzjeYAS7sc3p4k3vIdQIac4L4J6MUyfSbYzJSIAv_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp"],"datasets":[{"label":"","data":[3,2,2,2,2,2,2,2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[7.69,5.13,5.13,5.13,5.13,5.13,5.13,5.13,5.13,5.13,2.56,2.56,2.56,2.56,2.56,2.56,2.56,2.56,2.56,2.56,2.56,2.56,2.56,2.56,2.56,2.56,2.56,2.56],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","Wiley","American Chemical Society (ACS)","Springer Nature","IOP Publishing","Taylor & Francis","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[17,11,40,8,2075,18,9422],"codes":[0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/LsKy6OnmmmRGcAU6CZgWQvNiP1polbaSLNrN7zqj_medium.webp","\/storage\/images\/resized\/5YZtvLvkPZuc2JHOaZsjCvGSHFCuC3drUwN3YAc5_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[13,10,9,4,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[33.33,25.64,23.08,10.26,2.56,2.56,2.56],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0],"percentage":["0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,1],"percentage":["0","2.56"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,4],"percentage":["0","10.26"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[8,24],"percentage":["20.51","61.54"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,2],"percentage":["0","5.13"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,2],"percentage":["0","5.13"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,3],"percentage":["0","7.69"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,2],"percentage":["0","5.13"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[8,22],"percentage":["20.51","56.41"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,2],"percentage":["0","5.13"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Fang R. et al. Achieving stable all-solid-state lithium-metal batteries by tuning the cathode-electrolyte interface and ionic/electronic transport within the cathode // Materials Today. 2023. Vol. 64. pp. 52-60.

GOST all authors (up to 50) Copy

Fang R., Liu Y., Li Y., Manthiram A., Goodenough J. B. Achieving stable all-solid-state lithium-metal batteries by tuning the cathode-electrolyte interface and ionic/electronic transport within the cathode // Materials Today. 2023. Vol. 64. pp. 52-60.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.mattod.2023.03.001

UR - https://doi.org/10.1016/j.mattod.2023.03.001

TI - Achieving stable all-solid-state lithium-metal batteries by tuning the cathode-electrolyte interface and ionic/electronic transport within the cathode

T2 - Materials Today

AU - Fang, Ruyi

AU - Liu, Yijie

AU - Li, Y.

AU - Manthiram, Arumugam

AU - Goodenough, John B.

PY - 2023

DA - 2023/04/01 00:00:00

PB - Elsevier

SP - 52-60

VL - 64

SN - 1369-7021

ER -

BibTex

Cite this

BibTex Copy

@article{2023_Fang,

author = {Ruyi Fang and Yijie Liu and Y. Li and Arumugam Manthiram and John B. Goodenough},

title = {Achieving stable all-solid-state lithium-metal batteries by tuning the cathode-electrolyte interface and ionic/electronic transport within the cathode},

journal = {Materials Today},

year = {2023},

volume = {64},

publisher = {Elsevier},

month = {apr},

url = {https://doi.org/10.1016/j.mattod.2023.03.001},

pages = {52--60},

doi = {10.1016/j.mattod.2023.03.001}

}

Found error?

Publisher

Elsevier

Journal

Materials Today

Quartile SCImago

Quartile WOS

Impact factor

24.2

ISSN

13697021 (Print)

Profiles