Gas permeability properties of decorated MCM-41/polyethylene hybrids prepared by in-situ polymerization
Artur Bento
1
,
J P Lourenço
2
,
A. Fernandes
3
,
Maria do Rosário Ribeiro
1
,
Javier Arranz-Andres
4, 5
,
V. Lorenzo
6
,
Maria L. Cerrada
4, 5
4
Instituto de Ciencia y Tecnología de Polímeros (ICTP-CSIC)
|
5
Juan de la Cierva, 3 Madrid 28006 Spain
|
Publication type: Journal Article
Publication date: 2012-10-01
scimago Q1
wos Q1
SJR: 1.935
CiteScore: 17.1
Impact factor: 9.0
ISSN: 03767388, 18733123
Biochemistry
Physical and Theoretical Chemistry
General Materials Science
Filtration and Separation
Abstract
Mixed matrix membranes, MMM, based on polyethylene, PE, and silica mesoporous material, MCM-41, have been prepared using these hybrid materials obtained by in situ polymerization in order to achieve higher permeability, selectivity or both magnitudes relative to the existing polymeric PE membranes. Different methodologies are used to enhance interfacial adhesion between components, PE matrix and MCM-41. These basically consist of promoting the modification of MCM-41 surface with undecenoic acid, UA/triisobutylaluminum, TIBA, system before the polymerization and of incorporating UA in the polymer chains by copolymerization. The influence of UA on the degradation behavior is evaluated for all of the hybrids and the transport properties, in terms of permeability and diffusivity coefficients as well as permselectivity at different gases and temperatures are checked in some of the resulting materials.
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Total citations:
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Citations from 2024:
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GOST
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Bento A. et al. Gas permeability properties of decorated MCM-41/polyethylene hybrids prepared by in-situ polymerization // Journal of Membrane Science. 2012. Vol. 415-416. pp. 702-711.
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Bento A., Lourenço J. P., Fernandes A., Ribeiro M. D. R., Arranz-Andres J., Lorenzo V., Cerrada M. L. Gas permeability properties of decorated MCM-41/polyethylene hybrids prepared by in-situ polymerization // Journal of Membrane Science. 2012. Vol. 415-416. pp. 702-711.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.memsci.2012.05.058
UR - https://doi.org/10.1016/j.memsci.2012.05.058
TI - Gas permeability properties of decorated MCM-41/polyethylene hybrids prepared by in-situ polymerization
T2 - Journal of Membrane Science
AU - Bento, Artur
AU - Lourenço, J P
AU - Fernandes, A.
AU - Ribeiro, Maria do Rosário
AU - Arranz-Andres, Javier
AU - Lorenzo, V.
AU - Cerrada, Maria L.
PY - 2012
DA - 2012/10/01
PB - Elsevier
SP - 702-711
VL - 415-416
SN - 0376-7388
SN - 1873-3123
ER -
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BibTex (up to 50 authors)
Copy
@article{2012_Bento,
author = {Artur Bento and J P Lourenço and A. Fernandes and Maria do Rosário Ribeiro and Javier Arranz-Andres and V. Lorenzo and Maria L. Cerrada},
title = {Gas permeability properties of decorated MCM-41/polyethylene hybrids prepared by in-situ polymerization},
journal = {Journal of Membrane Science},
year = {2012},
volume = {415-416},
publisher = {Elsevier},
month = {oct},
url = {https://doi.org/10.1016/j.memsci.2012.05.058},
pages = {702--711},
doi = {10.1016/j.memsci.2012.05.058}
}