Journal of Membrane Science, volume 595, pages 117538
Poly(ethylene oxide)-based composite solid polymer electrolyte containing Li7La3Zr2O12 and poly(ethylene glycol) dimethyl ether
Ji Hye Cha
1
,
Pravin N. Didwal
,
Pravin N Didwal
2
,
Ju Min Kim
,
Ju Yon Kim
1
,
Duck-Rye Chang
,
Duck Rye Chang
1
,
Chan-Jin Park
,
Chan-Jin Park
2
Publication type: Journal Article
Publication date: 2020-02-01
Journal:
Journal of Membrane Science
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.5
ISSN: 03767388
Biochemistry
Physical and Theoretical Chemistry
General Materials Science
Filtration and Separation
Abstract
We have synthesized a self-standing, flexible, highly ion conductive, and electrochemically stable composite solid polymer electrolyte (CSPE) composed of a poly(ethylene oxide) matrix, Li7La3Zr2O12 ceramic filler, and poly(ethylene glycol) dimethyl ether (PEGDME) plasticizer for all-solid-state Li-ion batteries. The CSPE containing 10 wt% PEGDME (CSPE10) shows the highest ionic conductivity of 4.7 × 10-4 S cm-1 at 60 °C. Additionally, all the CSPEs are stable up to 5.0 V vs. Li/Li+, and CSPE10 shows a high Li-ion transference number of 0.48 at 60 °C. When Li/CSPE/Li symmetric cells are cyclically polarized, the cell with CSPE10 shows the smallest overpotential because of the high ionic conductivity of CSPE10 and the low interfacial resistance between Li and CSPE10. The all-solid-state full cell with the Li/CSPE10/LiNi0.6Co0.2Mn0.2O2 configuration delivers an initial discharge capacity of 157 mA h g-1 at 0.1C at 60 °C. Even after 100 cycles at a higher C-rate of 0.5C, the full cell maintains high discharge capacity of 116 mA h g-1 corresponding to a capacity retention of ~86%. The full cell with a high LiNi0.6Co0.2Mn0.2O2 mass loading of 7.7 mg cm-2 shows an initial discharge capacity of ~160 mA h g-1 and maintains high discharge capacity of 140 mA h g-1 even after 60 cycles.
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Citations by publishers
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Elsevier
29 publications, 42.03%
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Wiley
12 publications, 17.39%
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American Chemical Society (ACS)
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6 publications, 8.7%
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2 publications, 2.9%
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Springer Nature
2 publications, 2.9%
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2 publications, 2.9%
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The Electrochemical Society
1 publication, 1.45%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.45%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Cha J. H. et al. Poly(ethylene oxide)-based composite solid polymer electrolyte containing Li7La3Zr2O12 and poly(ethylene glycol) dimethyl ether // Journal of Membrane Science. 2020. Vol. 595. p. 117538.
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Cha J. H., Didwal P. N., Didwal P. N., Kim J. M., Kim J. Y., Chang D., Chang D. R., Park C., Park C. Poly(ethylene oxide)-based composite solid polymer electrolyte containing Li7La3Zr2O12 and poly(ethylene glycol) dimethyl ether // Journal of Membrane Science. 2020. Vol. 595. p. 117538.
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TY - JOUR
DO - 10.1016/j.memsci.2019.117538
UR - https://doi.org/10.1016/j.memsci.2019.117538
TI - Poly(ethylene oxide)-based composite solid polymer electrolyte containing Li7La3Zr2O12 and poly(ethylene glycol) dimethyl ether
T2 - Journal of Membrane Science
AU - Cha, Ji Hye
AU - Didwal, Pravin N.
AU - Kim, Ju Min
AU - Chang, Duck-Rye
AU - Park, Chan-Jin
AU - Didwal, Pravin N
AU - Kim, Ju Yon
AU - Chang, Duck Rye
AU - Park, Chan-Jin
PY - 2020
DA - 2020/02/01 00:00:00
PB - Elsevier
SP - 117538
VL - 595
SN - 0376-7388
ER -
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@article{2020_Cha,
author = {Ji Hye Cha and Pravin N. Didwal and Ju Min Kim and Duck-Rye Chang and Chan-Jin Park and Pravin N Didwal and Ju Yon Kim and Duck Rye Chang and Chan-Jin Park},
title = {Poly(ethylene oxide)-based composite solid polymer electrolyte containing Li7La3Zr2O12 and poly(ethylene glycol) dimethyl ether},
journal = {Journal of Membrane Science},
year = {2020},
volume = {595},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/j.memsci.2019.117538},
pages = {117538},
doi = {10.1016/j.memsci.2019.117538}
}