Journal of Membrane Science, volume 601, pages 117918
Membranes with novel highly-delocalized sulfonylimide anions for lithium-ion batteries
3
MemBrain s. r. o., (Membrane Innovation Centre), Pod Vinicí 87, 471 27, Stráž Pod Ralskem, Czech Republic
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Publication type: Journal Article
Publication date: 2020-03-01
Journal:
Journal of Membrane Science
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.5
ISSN: 03767388
Biochemistry
Physical and Theoretical Chemistry
General Materials Science
Filtration and Separation
Abstract
Cation-exchange membranes containing sulfo R–SO3M and sulfonylimide functional groups [R–SO2NSO2–X]M, where X=CCl3, CF3, Ph, p-NO2Ph, p-CF3Ph and M+=Li/Na/H, have been synthesized by the Hinsberg reaction from the polystyrene-block-poly(ethylene-ran-butylene)-block-polystyrene block copolymer. The obtained membranes have been characterized using ATR IR spectroscopy, CHNS elemental analysis, TGA, DSC, SEM and X-ray diffraction analysis, as well as mechanical properties were determined. Ionic conductivity of plasticized polymer electrolytes, containing mixtures of ethylene carbonate, propylene carbonate and ethylene carbonate, dimethylacetamide were investigated by impedance spectroscopy. It was demonstrated that membranes containing trifluorosulfonylimide functional groups have the highest ionic conductivity. The maximum ionic conductivity at 25 °C was observed for the membrane in contact with an ethylene carbonate – dimethylacetamide mixture.
Top-30
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1 publication, 9.09%
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Citations by publishers
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3
4
5
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Elsevier
5 publications, 45.45%
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2 publications, 18.18%
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Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 18.18%
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Wiley
2 publications, 18.18%
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Voropaeva D. et al. Membranes with novel highly-delocalized sulfonylimide anions for lithium-ion batteries // Journal of Membrane Science. 2020. Vol. 601. p. 117918.
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Voropaeva D., Golubenko D., Merkel A., Yaroslavtsev A. B. Membranes with novel highly-delocalized sulfonylimide anions for lithium-ion batteries // Journal of Membrane Science. 2020. Vol. 601. p. 117918.
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TY - JOUR
DO - 10.1016/j.memsci.2020.117918
UR - https://linkinghub.elsevier.com/retrieve/pii/S0376738819335227
TI - Membranes with novel highly-delocalized sulfonylimide anions for lithium-ion batteries
T2 - Journal of Membrane Science
AU - Voropaeva, Daria
AU - Golubenko, Daniil
AU - Merkel, Arthur
AU - Yaroslavtsev, A. B.
PY - 2020
DA - 2020/03/01 00:00:00
PB - Elsevier
SP - 117918
VL - 601
SN - 0376-7388
ER -
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@article{2020_Voropaeva,
author = {Daria Voropaeva and Daniil Golubenko and Arthur Merkel and A. B. Yaroslavtsev},
title = {Membranes with novel highly-delocalized sulfonylimide anions for lithium-ion batteries},
journal = {Journal of Membrane Science},
year = {2020},
volume = {601},
publisher = {Elsevier},
month = {mar},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0376738819335227},
pages = {117918},
doi = {10.1016/j.memsci.2020.117918}
}