Journal of Membrane Science, volume 610, pages 118265

A composite solid electrolyte with a framework of vertically aligned perovskite for all-solid-state Li-metal batteries

Ke Liu ¹

Maochun Wu ¹

Lei Wei ¹

Yanke Lin ¹

Tianshou Zhao ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Department of Mechanical and Aerospace Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon,Hong Kong,China |

Publication type: Journal Article

Publication date: 2020-09-01

Elsevier

Journal: Journal of Membrane Science

Quartile SCImago

Quartile WOS

Impact factor: 9.5

ISSN: 03767388

DOI: 10.1016/j.memsci.2020.118265

Copy DOI

Biochemistry

Physical and Theoretical Chemistry

General Materials Science

Filtration and Separation

Abstract

Composite solid electrolytes (CSEs), which inherit the flexibility of polymer electrolytes and the high ionic conductivity of ceramic electrolytes, hold a great potential to realize all-solid-state Li-metal batteries (ASSLMBs) with high energy density and enhanced safety. However, conventional preparation methods for CSEs by randomly dispersing ceramic particles in a polymer matrix fail to provide effective Li + conducting networks, thus severely sacrificing the high ionic conductivity of ceramic fillers. In this work, we develop a framework of vertically aligned perovskite Li 0.33 La 0.557 TiO 3 (LLTO) embedded in a PEO-LiTFSI matrix to maximize the ionic conduction. The vertically aligned LLTO structure prepared by an ice-templating method provides fast, continuous and the shortest pathways for Li + transport, thus boosting the ionic conductivity from 0.038 to 0.13 mS cm −1 . As a result, a Li | LiFePO 4 full battery assembled with the developed CSE is capable of delivering a specific discharge capacity of 144.6 mAh g −1 at 1 C at 60 °C with a high capacity retention of 96.0% after 100 cycles. • A framework of vertically aligned Li 0.33 La 0.557 TiO 3 is developed for CSEs. • The Li 0.33 La 0.557 TiO 3 framework boosts the ionic conductivity to 0.13 mS cm −1 . • An ASSLMB delivers a specific capacity of 144.6 mAh g −1 at 1 C at 60 °C.

By date By citations

Top-30

Citations by journals

	1 2 3 4
Journal of Membrane Science	Journal of Membrane Science, 4, 9.52% Journal of Membrane Science 4 publications, 9.52%
ACS Applied Energy Materials	ACS Applied Energy Materials, 3, 7.14% ACS Applied Energy Materials 3 publications, 7.14%
Electrochimica Acta	Electrochimica Acta, 2, 4.76% Electrochimica Acta 2 publications, 4.76%
Chemical Engineering Journal	Chemical Engineering Journal, 2, 4.76% Chemical Engineering Journal 2 publications, 4.76%
Journal of Energy Chemistry	Journal of Energy Chemistry, 2, 4.76% Journal of Energy Chemistry 2 publications, 4.76%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 2, 4.76% Journal of Materials Chemistry A 2 publications, 4.76%
Materials	Materials, 2, 4.76% Materials 2 publications, 4.76%
Nano-Micro Letters	Nano-Micro Letters, 1, 2.38% Nano-Micro Letters 1 publication, 2.38%
Small	Small, 1, 2.38% Small 1 publication, 2.38%
Batteries	Batteries, 1, 2.38% Batteries 1 publication, 2.38%
Electrochemical Energy Reviews	Electrochemical Energy Reviews, 1, 2.38% Electrochemical Energy Reviews 1 publication, 2.38%
JOM	JOM, 1, 2.38% JOM 1 publication, 2.38%
Particuology	Particuology, 1, 2.38% Particuology 1 publication, 2.38%
Journal of Industrial and Engineering Chemistry	Journal of Industrial and Engineering Chemistry, 1, 2.38% Journal of Industrial and Engineering Chemistry 1 publication, 2.38%
Materials Today Sustainability	Materials Today Sustainability, 1, 2.38% Materials Today Sustainability 1 publication, 2.38%
Composite Structures	Composite Structures, 1, 2.38% Composite Structures 1 publication, 2.38%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 1, 2.38% Journal of Alloys and Compounds 1 publication, 2.38%
Solid State Ionics	Solid State Ionics, 1, 2.38% Solid State Ionics 1 publication, 2.38%
SusMat	SusMat, 1, 2.38% SusMat 1 publication, 2.38%
Chemistry - An Asian Journal	Chemistry - An Asian Journal, 1, 2.38% Chemistry - An Asian Journal 1 publication, 2.38%
ChemNanoMat	ChemNanoMat, 1, 2.38% ChemNanoMat 1 publication, 2.38%
ChemistrySelect	ChemistrySelect, 1, 2.38% ChemistrySelect 1 publication, 2.38%
ACS applied materials & interfaces	ACS applied materials & interfaces, 1, 2.38% ACS applied materials & interfaces 1 publication, 2.38%
Progress in Materials Science	Progress in Materials Science, 1, 2.38% Progress in Materials Science 1 publication, 2.38%
Dalton Transactions	Dalton Transactions, 1, 2.38% Dalton Transactions 1 publication, 2.38%
EcoEnergy	EcoEnergy, 1, 2.38% EcoEnergy 1 publication, 2.38%
Frontiers in Energy Research	Frontiers in Energy Research, 1, 2.38% Frontiers in Energy Research 1 publication, 2.38%
Materials Today Chemistry	Materials Today Chemistry, 1, 2.38% Materials Today Chemistry 1 publication, 2.38%
Colloids and Surfaces A: Physicochemical and Engineering Aspects	Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1, 2.38% Colloids and Surfaces A: Physicochemical and Engineering Aspects 1 publication, 2.38%
eScience	eScience, 1, 2.38% eScience 1 publication, 2.38%
	1 2 3 4

Citations by publishers

	2 4 6 8 10 12 14 16 18 20
Elsevier	Elsevier, 19, 45.24% Elsevier 19 publications, 45.24%
Wiley	Wiley, 7, 16.67% Wiley 7 publications, 16.67%
American Chemical Society (ACS)	American Chemical Society (ACS), 4, 9.52% American Chemical Society (ACS) 4 publications, 9.52%
Springer Nature	Springer Nature, 3, 7.14% Springer Nature 3 publications, 7.14%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 3, 7.14% Multidisciplinary Digital Publishing Institute (MDPI) 3 publications, 7.14%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 3, 7.14% Royal Society of Chemistry (RSC) 3 publications, 7.14%
Korean Society of Industrial Engineering Chemistry	Korean Society of Industrial Engineering Chemistry, 1, 2.38% Korean Society of Industrial Engineering Chemistry 1 publication, 2.38%
Frontiers Media S.A.	Frontiers Media S.A., 1, 2.38% Frontiers Media S.A. 1 publication, 2.38%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 2.38% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 2.38%
	2 4 6 8 10 12 14 16 18 20

We do not take into account publications without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2020,2021,2022,2023,2024],"ids":[0,0,0,0,0],"codes":[0,0,0,0,0],"imageUrls":["","","","",""],"datasets":[{"label":"Citations number","data":[1,11,9,11,10],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["2.38","26.19","21.43","26.19","23.81"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Journal of Membrane Science","ACS Applied Energy Materials","Electrochimica Acta","Chemical Engineering Journal","Journal of Energy Chemistry","Journal of Materials Chemistry A","Materials","Nano-Micro Letters","Small","Batteries","Electrochemical Energy Reviews","JOM","Particuology","Journal of Industrial and Engineering Chemistry","Materials Today Sustainability","Composite Structures","Journal of Alloys and Compounds","Solid State Ionics","SusMat","Chemistry - An Asian Journal","ChemNanoMat","ChemistrySelect","ACS applied materials & interfaces","Progress in Materials Science","Dalton Transactions","EcoEnergy","Frontiers in Energy Research","Materials Today Chemistry","Colloids and Surfaces A: Physicochemical and Engineering Aspects","eScience"],"ids":[20733,6419,15613,16275,20653,14919,25198,7765,9872,19798,25884,17279,25094,1786,10882,24447,4015,12542,28603,10120,15836,8021,1458,21250,8473,55176,13537,1350,21908,28252],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/4QWA67eqfcfyOiA8Wk7YnqroHFqQbTsmDJUYTCTg_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp"],"datasets":[{"label":"","data":[4,3,2,2,2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[9.52,7.14,4.76,4.76,4.76,4.76,4.76,2.38,2.38,2.38,2.38,2.38,2.38,2.38,2.38,2.38,2.38,2.38,2.38,2.38,2.38,2.38,2.38,2.38,2.38,2.38,2.38,2.38,2.38,2.38],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","Wiley","American Chemical Society (ACS)","Springer Nature","Multidisciplinary Digital Publishing Institute (MDPI)","Royal Society of Chemistry (RSC)","Korean Society of Industrial Engineering Chemistry","Frontiers Media S.A.","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[17,11,40,8,202,123,709,208,9422],"codes":[0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","","\/storage\/images\/resized\/4QWA67eqfcfyOiA8Wk7YnqroHFqQbTsmDJUYTCTg_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[19,7,4,3,3,3,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[45.24,16.67,9.52,7.14,7.14,7.14,2.38,2.38,2.38],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0],"percentage":["0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0,0,0],"percentage":["0","0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,2,2,1,2],"percentage":["2.38","4.76","4.76","2.38","4.76"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[0,9,6,9,7],"percentage":["0","21.43","14.29","21.43","16.67"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,1,1,1],"percentage":["0","0","2.38","2.38","2.38"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0],"percentage":["0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,1,1,0],"percentage":["0","0","2.38","2.38","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,4,3,0,3],"percentage":["2.38","9.52","7.14","0","7.14"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[0,7,4,9,6],"percentage":["0","16.67","9.52","21.43","14.29"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[0,0,1,1,1],"percentage":["0","0","2.38","2.38","2.38"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Liu K. et al. A composite solid electrolyte with a framework of vertically aligned perovskite for all-solid-state Li-metal batteries // Journal of Membrane Science. 2020. Vol. 610. p. 118265.

GOST all authors (up to 50) Copy

Liu K., Wu M., Wei L., Lin Y., Zhao T. A composite solid electrolyte with a framework of vertically aligned perovskite for all-solid-state Li-metal batteries // Journal of Membrane Science. 2020. Vol. 610. p. 118265.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1016/j.memsci.2020.118265

UR - https://doi.org/10.1016/j.memsci.2020.118265

TI - A composite solid electrolyte with a framework of vertically aligned perovskite for all-solid-state Li-metal batteries

T2 - Journal of Membrane Science

AU - Liu, Ke

AU - Wu, Maochun

AU - Wei, Lei

AU - Lin, Yanke

AU - Zhao, Tianshou

PY - 2020

DA - 2020/09/01 00:00:00

PB - Elsevier

SP - 118265

VL - 610

SN - 0376-7388

ER -

BibTex

Cite this

BibTex Copy

@article{2020_Liu,

author = {Ke Liu and Maochun Wu and Lei Wei and Yanke Lin and Tianshou Zhao},

title = {A composite solid electrolyte with a framework of vertically aligned perovskite for all-solid-state Li-metal batteries},

journal = {Journal of Membrane Science},

year = {2020},

volume = {610},

publisher = {Elsevier},

month = {sep},

url = {https://doi.org/10.1016/j.memsci.2020.118265},

pages = {118265},

doi = {10.1016/j.memsci.2020.118265}

}

Found error?

Publisher

Elsevier

Journal

Journal of Membrane Science

Quartile SCImago

Quartile WOS

Impact factor

9.5

ISSN

03767388 (Print)