Mendeleev Communications
,  volume 27 ,  issue 3 ,  pages 243-245

Spontaneous reaction of malonyl peroxides with methanol

Margarita A. Lapitskaya 1
, 
Vera A. Vil’ 1
, 
Ludmila L Vasileva 1
, 
Elena D Daeva 1
, 
Alexander O. Terent'ev 1
, 
Kasimir K. Pivnitsky 1
1
 
Publication type: Journal Article
Publication date: 2017-05-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
The spontaneous reaction of disubstituted malonyl peroxides (MPOs) with methanol affording monopermalonic acid monomethyl esters is fast (minutes) for lower homologues but is sharply decelerated (days) for the higher ones. Spirocyclopropyl-MPO is an exception in which the nucleophilic opening of the spiroactivated cyclopropane ring leads to 2,4-dimethoxy-2-carboxybutanoic acid.
Found 
Found 

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Lapitskaya M. A. et al. Spontaneous reaction of malonyl peroxides with methanol // Mendeleev Communications. 2017. Vol. 27. No. 3. pp. 243-245.
GOST all authors (up to 50) Copy
Lapitskaya M. A., Vil’ V. A., Vasileva L. L., Daeva E. D., Terent'ev A. O., Pivnitsky K. K. Spontaneous reaction of malonyl peroxides with methanol // Mendeleev Communications. 2017. Vol. 27. No. 3. pp. 243-245.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2017.05.008
UR - https://doi.org/10.1016/j.mencom.2017.05.008
TI - Spontaneous reaction of malonyl peroxides with methanol
T2 - Mendeleev Communications
AU - Lapitskaya, Margarita A.
AU - Vil’, Vera A.
AU - Vasileva, Ludmila L
AU - Daeva, Elena D
AU - Terent'ev, Alexander O.
AU - Pivnitsky, Kasimir K.
PY - 2017
DA - 2017/05/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 243-245
IS - 3
VL - 27
SN - 0959-9436
SN - 1364-551X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2017_Lapitskaya,
author = {Margarita A. Lapitskaya and Vera A. Vil’ and Ludmila L Vasileva and Elena D Daeva and Alexander O. Terent'ev and Kasimir K. Pivnitsky},
title = {Spontaneous reaction of malonyl peroxides with methanol},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {may},
url = {https://doi.org/10.1016/j.mencom.2017.05.008},
number = {3},
pages = {243--245},
doi = {10.1016/j.mencom.2017.05.008}
}
MLA
Cite this
MLA Copy
Lapitskaya, Margarita A., et al. “Spontaneous reaction of malonyl peroxides with methanol.” Mendeleev Communications, vol. 27, no. 3, May. 2017, pp. 243-245. https://doi.org/10.1016/j.mencom.2017.05.008.