Mendeleev Communications
,  том 28 ,  издание 3 ,  страницы 278-280

Crystal and molecular structures of Si -(iodomethyl)silatranes with methyl substituents in β-position relative to the nitrogen atom

Тип публикации: Journal Article
Дата публикации: 2018-05-26
scimago Q3
wos Q3
БС1
SJR: 0.305
CiteScore: 3
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Краткое описание
Crystal and molecular structures of two silatranes, 1-iodomethyl-3-methyl- and 1-iodomethyl-3,7,10-trimethyl-2,8,9-trioxa-5-aza-1-silabicyclo[3.3.3]undecanes, were determined by X-ray analysis. Comparison of their structural and geometrical characteristics with those of other silatranes shows that the presence of methyl substituents β-positioned to nitrogen atoms increases the length of the dative Si←N bond, whereas the introduction of iodine into the axial position of the silatrane slightly decreases the length of the Si←N bond.
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Smirnov V. et al. Crystal and molecular structures of Si -(iodomethyl)silatranes with methyl substituents in β-position relative to the nitrogen atom // Mendeleev Communications. 2018. Vol. 28. No. 3. pp. 278-280.
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Smirnov V., Zelbst E. A., Kuznetzova G. A., Sterkhova I. Crystal and molecular structures of Si -(iodomethyl)silatranes with methyl substituents in β-position relative to the nitrogen atom // Mendeleev Communications. 2018. Vol. 28. No. 3. pp. 278-280.
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TY - JOUR
DO - 10.1016/j.mencom.2018.05.016
UR - https://doi.org/10.1016/j.mencom.2018.05.016
TI - Crystal and molecular structures of Si -(iodomethyl)silatranes with methyl substituents in β-position relative to the nitrogen atom
T2 - Mendeleev Communications
AU - Smirnov, Vladimir
AU - Zelbst, Eleonora A
AU - Kuznetzova, Galina A
AU - Sterkhova, Irina
PY - 2018
DA - 2018/05/26
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 278-280
IS - 3
VL - 28
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2018_Smirnov,
author = {Vladimir Smirnov and Eleonora A Zelbst and Galina A Kuznetzova and Irina Sterkhova},
title = {Crystal and molecular structures of Si -(iodomethyl)silatranes with methyl substituents in β-position relative to the nitrogen atom},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {may},
url = {https://doi.org/10.1016/j.mencom.2018.05.016},
number = {3},
pages = {278--280},
doi = {10.1016/j.mencom.2018.05.016}
}
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Smirnov, Vladimir, et al. “Crystal and molecular structures of Si -(iodomethyl)silatranes with methyl substituents in β-position relative to the nitrogen atom.” Mendeleev Communications, vol. 28, no. 3, May. 2018, pp. 278-280. https://doi.org/10.1016/j.mencom.2018.05.016.