volume 28 issue 6 pages 606-608

First example of a click-reaction on the aminate copper complexes: effect of reaction parameters

Igor V Esarev 1
Anastasia V Laptenkova 2
Nicolay L Medvedskiy 1
Alexander I Ponyaev 1
Alexey V Eremin 1, 3
Rostislav E Trifonov 1, 5
Publication typeJournal Article
Publication date2018-11-01
scimago Q3
wos Q3
SJR0.305
CiteScore3.0
Impact factor1.7
ISSN09599436, 1364551X
General Chemistry
Abstract
The hydrothermal reaction of NaN3 with Cu(Phen)Cl2 in acetonitrile solutions results in the formation of two complexes: new d9 mononuclear cis-[CuII(Phen)2(mtz)2]·H2O and d10 coordination polymer catena-[CuI(Phen)(μ-CN)]n (mtz is 5-methyltetrazolate anion and Phen is 1,10-phenanthroline). The process involves in situ formation of mtz ligand via cycloaddition of acetonitrile and azide (in the case of [CuII(Phen)2(mtz)2]) and cleavage of acetonitrile C–C bond (in the case of [CuI(Phen)(μ-CN)]n). Both complexes were fully characterized by a comprehensive set of methods, including the single crystal X-ray diffraction data.
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Esarev I. V. et al. First example of a click-reaction on the aminate copper complexes: effect of reaction parameters // Mendeleev Communications. 2018. Vol. 28. No. 6. pp. 606-608.
GOST all authors (up to 50) Copy
Esarev I. V., Laptenkova A. V., Medvedskiy N. L., Ponyaev A. I., Eremin A. V., Gurzhiy V. V., Selyutin A., Poddel'sky A. I., Trifonov R. E. First example of a click-reaction on the aminate copper complexes: effect of reaction parameters // Mendeleev Communications. 2018. Vol. 28. No. 6. pp. 606-608.
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RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2018.11.014
UR - https://doi.org/10.1016/j.mencom.2018.11.014
TI - First example of a click-reaction on the aminate copper complexes: effect of reaction parameters
T2 - Mendeleev Communications
AU - Esarev, Igor V
AU - Laptenkova, Anastasia V
AU - Medvedskiy, Nicolay L
AU - Ponyaev, Alexander I
AU - Eremin, Alexey V
AU - Gurzhiy, Vladislav V.
AU - Selyutin, Artem
AU - Poddel'sky, Andrey I.
AU - Trifonov, Rostislav E
PY - 2018
DA - 2018/11/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 606-608
IS - 6
VL - 28
SN - 0959-9436
SN - 1364-551X
ER -
BibTex |
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@article{2018_Esarev,
author = {Igor V Esarev and Anastasia V Laptenkova and Nicolay L Medvedskiy and Alexander I Ponyaev and Alexey V Eremin and Vladislav V. Gurzhiy and Artem Selyutin and Andrey I. Poddel'sky and Rostislav E Trifonov},
title = {First example of a click-reaction on the aminate copper complexes: effect of reaction parameters},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {nov},
url = {https://doi.org/10.1016/j.mencom.2018.11.014},
number = {6},
pages = {606--608},
doi = {10.1016/j.mencom.2018.11.014}
}
MLA
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Esarev, Igor V., et al. “First example of a click-reaction on the aminate copper complexes: effect of reaction parameters.” Mendeleev Communications, vol. 28, no. 6, Nov. 2018, pp. 606-608. https://doi.org/10.1016/j.mencom.2018.11.014.