First example of a click-reaction on the aminate copper complexes: effect of reaction parameters
Igor V Esarev
1
,
Anastasia V Laptenkova
2
,
Nicolay L Medvedskiy
1
,
Alexander I Ponyaev
1
,
Alexey V Eremin
1, 3
,
Artem Selyutin
2
,
Rostislav E Trifonov
1, 5
1
3
Publication type: Journal Article
Publication date: 2018-11-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
The hydrothermal reaction of NaN3 with Cu(Phen)Cl2 in acetonitrile solutions results in the formation of two complexes: new d9 mononuclear cis-[CuII(Phen)2(mtz)2]·H2O and d10 coordination polymer catena-[CuI(Phen)(μ-CN)]n (mtz is 5-methyltetrazolate anion and Phen is 1,10-phenanthroline). The process involves in situ formation of mtz ligand via cycloaddition of acetonitrile and azide (in the case of [CuII(Phen)2(mtz)2]) and cleavage of acetonitrile C–C bond (in the case of [CuI(Phen)(μ-CN)]n). Both complexes were fully characterized by a comprehensive set of methods, including the single crystal X-ray diffraction data.
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Esarev I. V. et al. First example of a click-reaction on the aminate copper complexes: effect of reaction parameters // Mendeleev Communications. 2018. Vol. 28. No. 6. pp. 606-608.
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Esarev I. V., Laptenkova A. V., Medvedskiy N. L., Ponyaev A. I., Eremin A. V., Gurzhiy V. V., Selyutin A., Poddel'sky A. I., Trifonov R. E. First example of a click-reaction on the aminate copper complexes: effect of reaction parameters // Mendeleev Communications. 2018. Vol. 28. No. 6. pp. 606-608.
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TY - JOUR
DO - 10.1016/j.mencom.2018.11.014
UR - https://doi.org/10.1016/j.mencom.2018.11.014
TI - First example of a click-reaction on the aminate copper complexes: effect of reaction parameters
T2 - Mendeleev Communications
AU - Esarev, Igor V
AU - Laptenkova, Anastasia V
AU - Medvedskiy, Nicolay L
AU - Ponyaev, Alexander I
AU - Eremin, Alexey V
AU - Gurzhiy, Vladislav V.
AU - Selyutin, Artem
AU - Poddel'sky, Andrey I.
AU - Trifonov, Rostislav E
PY - 2018
DA - 2018/11/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 606-608
IS - 6
VL - 28
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2018_Esarev,
author = {Igor V Esarev and Anastasia V Laptenkova and Nicolay L Medvedskiy and Alexander I Ponyaev and Alexey V Eremin and Vladislav V. Gurzhiy and Artem Selyutin and Andrey I. Poddel'sky and Rostislav E Trifonov},
title = {First example of a click-reaction on the aminate copper complexes: effect of reaction parameters},
journal = {Mendeleev Communications},
year = {2018},
volume = {28},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {nov},
url = {https://doi.org/10.1016/j.mencom.2018.11.014},
number = {6},
pages = {606--608},
doi = {10.1016/j.mencom.2018.11.014}
}
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MLA
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Esarev, Igor V., et al. “First example of a click-reaction on the aminate copper complexes: effect of reaction parameters.” Mendeleev Communications, vol. 28, no. 6, Nov. 2018, pp. 606-608. https://doi.org/10.1016/j.mencom.2018.11.014.
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