Photoinduced deprotonation of cyclopentene oxide radical cations in low-temperature Freon matrices
1
Publication type: Journal Article
Publication date: 2020-01-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
Upon the photolysis (λ = 546 nm) of X-ray irradiated cyclopentene oxide/Freon solutions at 77 K, irreversible proton abstraction in the ring-open form of the cyclopentene oxide radical cation occurs, affecting the bridgehead carbon. This affords unstable 6-oxabicyclo[3.1.0]hexan-1-yl radicals, which undergo rearrangement to form ring-open terminal C-centered alkyl radicals detected as final products.
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Sorokin I. D. et al. Photoinduced deprotonation of cyclopentene oxide radical cations in low-temperature Freon matrices // Mendeleev Communications. 2020. Vol. 30. No. 1. pp. 67-69.
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Sorokin I. D., Gromov O. I., Pergushov V. I., Pomogailo D. A., Melnikov M. Y. Photoinduced deprotonation of cyclopentene oxide radical cations in low-temperature Freon matrices // Mendeleev Communications. 2020. Vol. 30. No. 1. pp. 67-69.
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TY - JOUR
DO - 10.1016/j.mencom.2020.01.022
UR - https://doi.org/10.1016/j.mencom.2020.01.022
TI - Photoinduced deprotonation of cyclopentene oxide radical cations in low-temperature Freon matrices
T2 - Mendeleev Communications
AU - Sorokin, Ivan D
AU - Gromov, O I
AU - Pergushov, Vladimir I
AU - Pomogailo, Daria A
AU - Melnikov, Mikhail Y.
PY - 2020
DA - 2020/01/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 67-69
IS - 1
VL - 30
SN - 0959-9436
SN - 1364-551X
ER -
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BibTex (up to 50 authors)
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@article{2020_Sorokin,
author = {Ivan D Sorokin and O I Gromov and Vladimir I Pergushov and Daria A Pomogailo and Mikhail Y. Melnikov},
title = {Photoinduced deprotonation of cyclopentene oxide radical cations in low-temperature Freon matrices},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jan},
url = {https://doi.org/10.1016/j.mencom.2020.01.022},
number = {1},
pages = {67--69},
doi = {10.1016/j.mencom.2020.01.022}
}
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MLA
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Sorokin, Ivan D., et al. “Photoinduced deprotonation of cyclopentene oxide radical cations in low-temperature Freon matrices.” Mendeleev Communications, vol. 30, no. 1, Jan. 2020, pp. 67-69. https://doi.org/10.1016/j.mencom.2020.01.022.