Mendeleev Communications
,  том 30 ,  издание 1 ,  страницы 67-69

Photoinduced deprotonation of cyclopentene oxide radical cations in low-temperature Freon matrices

Тип публикации: Journal Article
Дата публикации: 2020-01-01
scimago Q3
wos Q3
БС1
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Краткое описание
Upon the photolysis (λ = 546 nm) of X-ray irradiated cyclopentene oxide/Freon solutions at 77 K, irreversible proton abstraction in the ring-open form of the cyclopentene oxide radical cation occurs, affecting the bridgehead carbon. This affords unstable 6-oxabicyclo[3.1.0]hexan-1-yl radicals, which undergo rearrangement to form ring-open terminal C-centered alkyl radicals detected as final products.
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Sorokin I. D. et al. Photoinduced deprotonation of cyclopentene oxide radical cations in low-temperature Freon matrices // Mendeleev Communications. 2020. Vol. 30. No. 1. pp. 67-69.
ГОСТ со всеми авторами (до 50) Скопировать
Sorokin I. D., Gromov O. I., Pergushov V. I., Pomogailo D. A., Melnikov M. Y. Photoinduced deprotonation of cyclopentene oxide radical cations in low-temperature Freon matrices // Mendeleev Communications. 2020. Vol. 30. No. 1. pp. 67-69.
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TY - JOUR
DO - 10.1016/j.mencom.2020.01.022
UR - https://doi.org/10.1016/j.mencom.2020.01.022
TI - Photoinduced deprotonation of cyclopentene oxide radical cations in low-temperature Freon matrices
T2 - Mendeleev Communications
AU - Sorokin, Ivan D
AU - Gromov, O I
AU - Pergushov, Vladimir I
AU - Pomogailo, Daria A
AU - Melnikov, Mikhail Y.
PY - 2020
DA - 2020/01/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 67-69
IS - 1
VL - 30
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2020_Sorokin,
author = {Ivan D Sorokin and O I Gromov and Vladimir I Pergushov and Daria A Pomogailo and Mikhail Y. Melnikov},
title = {Photoinduced deprotonation of cyclopentene oxide radical cations in low-temperature Freon matrices},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jan},
url = {https://doi.org/10.1016/j.mencom.2020.01.022},
number = {1},
pages = {67--69},
doi = {10.1016/j.mencom.2020.01.022}
}
MLA
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Sorokin, Ivan D., et al. “Photoinduced deprotonation of cyclopentene oxide radical cations in low-temperature Freon matrices.” Mendeleev Communications, vol. 30, no. 1, Jan. 2020, pp. 67-69. https://doi.org/10.1016/j.mencom.2020.01.022.