Superbase-promoted multi-molecular acetylene/arylamine self-organization to 1-arylpyrroles
Elena Yu Schmidt
1
,
Nadezhda Semenova
2, 3, 4, 5, 6
,
E. V. Ivanova
2, 3, 4, 5, 6
,
Ivan A Bidusenko
2, 3, 4, 5, 6
,
B. A. Trofimov
2, 3, 4, 5, 6
3
Siberian branch of the Russian Academy of sciences
4
664033
5
Irkutsk
|
6
RUSSIAN FEDERATION
|
Publication type: Journal Article
Publication date: 2020-01-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
A new superbase-promoted reaction of acetylene involves self-organization of its three molecules with one molecule of arylamine in KOH/DMSO system to afford 1-aryl-2,5- dimethylpyrroles in up to 63% yields. The key step of this reaction cascade is assumed to be the nucleophilic addition of acetylene to the C = N bond of the intermediate aldimine (aza-Favorsky reaction).
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GOST
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Schmidt E. Yu. et al. Superbase-promoted multi-molecular acetylene/arylamine self-organization to 1-arylpyrroles // Mendeleev Communications. 2020. Vol. 30. No. 1. pp. 109-111.
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Schmidt E. Yu., Semenova N., Ivanova E. V., Bidusenko I. A., Trofimov B. A. Superbase-promoted multi-molecular acetylene/arylamine self-organization to 1-arylpyrroles // Mendeleev Communications. 2020. Vol. 30. No. 1. pp. 109-111.
Cite this
RIS
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TY - JOUR
DO - 10.1016/j.mencom.2020.01.036
UR - https://doi.org/10.1016/j.mencom.2020.01.036
TI - Superbase-promoted multi-molecular acetylene/arylamine self-organization to 1-arylpyrroles
T2 - Mendeleev Communications
AU - Schmidt, Elena Yu
AU - Semenova, Nadezhda
AU - Ivanova, E. V.
AU - Bidusenko, Ivan A
AU - Trofimov, B. A.
PY - 2020
DA - 2020/01/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 109-111
IS - 1
VL - 30
SN - 0959-9436
SN - 1364-551X
ER -
Cite this
BibTex (up to 50 authors)
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@article{2020_Schmidt,
author = {Elena Yu Schmidt and Nadezhda Semenova and E. V. Ivanova and Ivan A Bidusenko and B. A. Trofimov},
title = {Superbase-promoted multi-molecular acetylene/arylamine self-organization to 1-arylpyrroles},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jan},
url = {https://doi.org/10.1016/j.mencom.2020.01.036},
number = {1},
pages = {109--111},
doi = {10.1016/j.mencom.2020.01.036}
}
Cite this
MLA
Copy
Schmidt, Elena Yu., et al. “Superbase-promoted multi-molecular acetylene/arylamine self-organization to 1-arylpyrroles.” Mendeleev Communications, vol. 30, no. 1, Jan. 2020, pp. 109-111. https://doi.org/10.1016/j.mencom.2020.01.036.