volume 30 issue 3 pages 279-281

Theoretical assessment of thermodynamic stability of 2D octane-1,8-diammonium lead halide perovskites

Publication typeJournal Article
Publication date2020-05-01
scimago Q3
wos Q3
SJR0.305
CiteScore3.0
Impact factor1.7
ISSN09599436, 1364551X
General Chemistry
Abstract
Two-dimensional (2D) lead halide perovskites are promising materials for photovoltaics due to a combination of excellent functional properties and improved stability as compared to their 3D analogues. A thermodynamic stability of the 2D octane-1,8-diammonium-based perovskites containing one to four layers has been assessed using a semi-empirical approach. Revealed values of the standard enthalpy of formation are essentially negative, while the dependence of enthalpy on the number of layers is not linear, so the perovskites with the even number of layers seem to be much more stable due to the features of their crystal and local structures.
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Marchenko E. et al. Theoretical assessment of thermodynamic stability of 2D octane-1,8-diammonium lead halide perovskites // Mendeleev Communications. 2020. Vol. 30. No. 3. pp. 279-281.
GOST all authors (up to 50) Copy
Marchenko E., Fateev S., Petrov A., Goodilin E. A., Tarasov A. Theoretical assessment of thermodynamic stability of 2D octane-1,8-diammonium lead halide perovskites // Mendeleev Communications. 2020. Vol. 30. No. 3. pp. 279-281.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2020.05.005
UR - https://doi.org/10.1016/j.mencom.2020.05.005
TI - Theoretical assessment of thermodynamic stability of 2D octane-1,8-diammonium lead halide perovskites
T2 - Mendeleev Communications
AU - Marchenko, Ekaterina
AU - Fateev, Sergey
AU - Petrov, Andrey
AU - Goodilin, Eugene A.
AU - Tarasov, Alexey
PY - 2020
DA - 2020/05/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 279-281
IS - 3
VL - 30
SN - 0959-9436
SN - 1364-551X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Marchenko,
author = {Ekaterina Marchenko and Sergey Fateev and Andrey Petrov and Eugene A. Goodilin and Alexey Tarasov},
title = {Theoretical assessment of thermodynamic stability of 2D octane-1,8-diammonium lead halide perovskites},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {may},
url = {https://doi.org/10.1016/j.mencom.2020.05.005},
number = {3},
pages = {279--281},
doi = {10.1016/j.mencom.2020.05.005}
}
MLA
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MLA Copy
Marchenko, Ekaterina, et al. “Theoretical assessment of thermodynamic stability of 2D octane-1,8-diammonium lead halide perovskites.” Mendeleev Communications, vol. 30, no. 3, May. 2020, pp. 279-281. https://doi.org/10.1016/j.mencom.2020.05.005.