Mendeleev Communications
,  том 30 ,  издание 4 ,  страницы 519-521

Metal ion directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine: steric and electronic restrictions

Тип публикации: Journal Article
Дата публикации: 2020-07-01
scimago Q3
wos Q3
БС1
SJR: 0.305
CiteScore: 3
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Краткое описание
A NiII-directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine results in formation of octahedral NiII complex, whose crystal structure has been resolved using single crystal X-ray diffraction. The structure indicates that only exocyclic enolic oxygen atom of the triketone takes part in the condensation with ethylenediamine. Quantum chemical calculations reveal insights into the observed reactivity of an initial NiII complex of 2-acetyl-1,3-indandione with ethylenediamine and point out steric effects as the main restriction for a complete cyclization into a tetraaza macrocycle.
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Ahmedova A., Zareva S., Dołęga A. Metal ion directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine: steric and electronic restrictions // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 519-521.
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Ahmedova A., Zareva S., Dołęga A. Metal ion directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine: steric and electronic restrictions // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 519-521.
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TY - JOUR
DO - 10.1016/j.mencom.2020.07.039
UR - https://doi.org/10.1016/j.mencom.2020.07.039
TI - Metal ion directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine: steric and electronic restrictions
T2 - Mendeleev Communications
AU - Ahmedova, Anife
AU - Zareva, Sonya
AU - Dołęga, Anna
PY - 2020
DA - 2020/07/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 519-521
IS - 4
VL - 30
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2020_Ahmedova,
author = {Anife Ahmedova and Sonya Zareva and Anna Dołęga},
title = {Metal ion directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine: steric and electronic restrictions},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jul},
url = {https://doi.org/10.1016/j.mencom.2020.07.039},
number = {4},
pages = {519--521},
doi = {10.1016/j.mencom.2020.07.039}
}
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Ahmedova, Anife, et al. “Metal ion directed template synthesis using 2-acetyl-1,3-indandione and ethylenediamine: steric and electronic restrictions.” Mendeleev Communications, vol. 30, no. 4, Jul. 2020, pp. 519-521. https://doi.org/10.1016/j.mencom.2020.07.039.