Mendeleev Communications
,  volume 31 ,  issue 1 ,  pages 46-47

Transition metal halide promoted hydride transfer in N,N-diisoalkyl-N-propargylamines

Publication type: Journal Article
Publication date: 2021-01-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
The reaction of N,N-diisopropyl-N-propargylamines with Et3Al/MXn system (MXn = CuCl, CuBr, ZnCl2, ZnI2, CdI2, TiCl4, ZrCl4, VCl5, TaCl5) in CH2Cl2 proceeds as an intramolecular red-ox hydride transfer affording N-dealkylated N-isopropyl-N-allylamines, allenes being formed as side products. The highest chemoselectivities and yields (71–89%) were attained by the application of new ZnI2/(MeAlO)n system.
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Sadykova F. T. et al. Transition metal halide promoted hydride transfer in N,N-diisoalkyl-N-propargylamines // Mendeleev Communications. 2021. Vol. 31. No. 1. pp. 46-47.
GOST all authors (up to 50) Copy
Sadykova F. T., Zosim T. P., Ramazanov I. R., Dzhemilev U. M. Transition metal halide promoted hydride transfer in N,N-diisoalkyl-N-propargylamines // Mendeleev Communications. 2021. Vol. 31. No. 1. pp. 46-47.
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RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2021.01.013
UR - https://doi.org/10.1016/j.mencom.2021.01.013
TI - Transition metal halide promoted hydride transfer in N,N-diisoalkyl-N-propargylamines
T2 - Mendeleev Communications
AU - Sadykova, Firuza T
AU - Zosim, Tatyana P
AU - Ramazanov, Ilfir R
AU - Dzhemilev, Usein M
PY - 2021
DA - 2021/01/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 46-47
IS - 1
VL - 31
SN - 0959-9436
SN - 1364-551X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Sadykova,
author = {Firuza T Sadykova and Tatyana P Zosim and Ilfir R Ramazanov and Usein M Dzhemilev},
title = {Transition metal halide promoted hydride transfer in N,N-diisoalkyl-N-propargylamines},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jan},
url = {https://doi.org/10.1016/j.mencom.2021.01.013},
number = {1},
pages = {46--47},
doi = {10.1016/j.mencom.2021.01.013}
}
MLA
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MLA Copy
Sadykova, Firuza T., et al. “Transition metal halide promoted hydride transfer in N,N-diisoalkyl-N-propargylamines.” Mendeleev Communications, vol. 31, no. 1, Jan. 2021, pp. 46-47. https://doi.org/10.1016/j.mencom.2021.01.013.