, volume 31 , issue 1 , pages 58-61

Halogen vs. ionic bonding: an unusual isomorphism between the neutral (C5Me5)2Fe/C2I2 cocrystal and ionic [(C5Me5)2Fe]Br3 crystal

Yu. V. Torubaev ¹

I. V. Skabitsky ¹

Georgy A Saratov ^{2, 3}

Petr Yu Barzilovich ⁴

Hide authors affiliations Show authors affiliations: 4 affiliations

N. S. Kurnakov Institute of General and Inorganic Chemistry Russian Academy of Sciences 119991 Moscow Russian Federation |

M. M. Shemyakin–Yu. A. Ovchinnikov Institute of Bioorganic Chemistry, Russian Academy of Sciences, 117997 Moscow, Russian Federation |

Moscow Institute of Physics and Technology, 141700 Dolgoprudny, Moscow Region, Russian Federation |

⁴

M. M. Shemyakin−Yu. A. Ovchinnikov Institute of Bioorganic Chemistry, Russian Academy of Sciences, 117997 Moscow, Russian Federation |

Publication type: Journal Article

Publication date: 2021-01-01

OOO Zhurnal "Mendeleevskie Soobshcheniya"

Mendeleev Communications

scimago Q3

wos Q3

SJR: 0.305

CiteScore: 3.0

Impact factor: 1.7

ISSN: 09599436, 1364551X

DOI: 10.1016/j.mencom.2021.01.017

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General Chemistry

Abstract

Almost equal molecular sizes of diiodoacetylene (C2I2) and the [Br3]− anion result in isomorphic neutral cocrystal (DMFc–C2I2) and [DMFc]+Br3− salt. This isomorphic pair of neutral and ionic crystals provides a unique example for the analysis of different types of bonding resulting in isotypic solid-state structures. Their energy frameworks visualize the obvious difference between their energetic structures: the lattice of DMFc–C2I2 is built upon the chains stabilized by I···(η5-C5Me5) halogen bonds; at the same time, [DMFc]+Br3− consists of electrostatically assembled layers associated by Br···π(Cp*) XBs interactions.

Found

8 citations

Adonin Sergey

DSc in Chemistry, professor

200 publications, 2 998 citations, 21 reviews

h-index: 30

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

A.E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences

South Ural State University

4 citations

Novikov Alexander

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PhD in Chemistry

411 publications, 8 100 citations, 251 reviews

h-index: 53

Saint Petersburg State University

Lomonosov Moscow State University

National Research University Higher School of Economics

Peoples' Friendship University of Russia

Research interests

Computational chemistry

Machine learning

Non-covalent Interactions

Quantum Chemistry

Reaction mechanisms

Supramolecular chemistry

3 citations

Bondarenko Mikhail

🤝

PhD in Chemistry

33 publications, 388 citations

h-index: 10

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

South Ural State University

Research interests

Coordination Chemistry

Halogen connection

Metal-organic coordination polymers

Supramolecular chemistry

2 citations

Zaguzin Alexander

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PhD in Chemistry

25 publications, 132 citations, 1 review

h-index: 8

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Research interests

Coordination Chemistry

Halogen connection

Metal-organic coordination polymers

Supramolecular chemistry

2 citations

Usoltsev Andrey

PhD in Chemistry

60 publications, 735 citations

h-index: 13

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

2 citations

Skabitskiy Ivan

PhD in Chemistry

76 publications, 546 citations

h-index: 13

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

1 citation

Abramov Pavel

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DSc in Chemistry, professor

277 publications, 3 831 citations, 61 reviews

h-index: 30

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

National Research Tomsk Polytechnic University

Research interests

Crystallography

1 citation

Sakhapov Ilyas

🥼 🤝

PhD in Chemistry

44 publications, 351 citations

h-index: 12

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Research interests

Electrochemistry

Green chemistry

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Torubaev Y. V. et al. Halogen vs. ionic bonding: an unusual isomorphism between the neutral (C5Me5)2Fe/C2I2 cocrystal and ionic [(C5Me5)2Fe]Br3 crystal // Mendeleev Communications. 2021. Vol. 31. No. 1. pp. 58-61.

GOST all authors (up to 50) Copy

Torubaev Y. V., Skabitsky I. V., Saratov G. A., Barzilovich P. Yu. Halogen vs. ionic bonding: an unusual isomorphism between the neutral (C5Me5)2Fe/C2I2 cocrystal and ionic [(C5Me5)2Fe]Br3 crystal // Mendeleev Communications. 2021. Vol. 31. No. 1. pp. 58-61.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.mencom.2021.01.017

UR - https://linkinghub.elsevier.com/retrieve/pii/S0959943621000171

TI - Halogen vs. ionic bonding: an unusual isomorphism between the neutral (C5Me5)2Fe/C2I2 cocrystal and ionic [(C5Me5)2Fe]Br3 crystal

T2 - Mendeleev Communications

AU - Torubaev, Yu. V.

AU - Skabitsky, I. V.

AU - Saratov, Georgy A

AU - Barzilovich, Petr Yu

PY - 2021

DA - 2021/01/01

PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"

SP - 58-61

IS - 1

VL - 31

SN - 0959-9436

SN - 1364-551X

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2021_Torubaev,

author = {Yu. V. Torubaev and I. V. Skabitsky and Georgy A Saratov and Petr Yu Barzilovich},

title = {Halogen vs. ionic bonding: an unusual isomorphism between the neutral (C5Me5)2Fe/C2I2 cocrystal and ionic [(C5Me5)2Fe]Br3 crystal},

journal = {Mendeleev Communications},

year = {2021},

volume = {31},

publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},

month = {jan},

url = {https://linkinghub.elsevier.com/retrieve/pii/S0959943621000171},

number = {1},

pages = {58--61},

doi = {10.1016/j.mencom.2021.01.017}

}

MLA

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MLA Copy

Torubaev, Yu. V., et al. “Halogen vs. ionic bonding: an unusual isomorphism between the neutral (C5Me5)2Fe/C2I2 cocrystal and ionic [(C5Me5)2Fe]Br3 crystal.” Mendeleev Communications, vol. 31, no. 1, Jan. 2021, pp. 58-61. https://linkinghub.elsevier.com/retrieve/pii/S0959943621000171.

Publisher

OOO Zhurnal "Mendeleevskie Soobshcheniya"

Journal

Mendeleev Communications

scimago Q3

wos Q3

SJR

0.305

CiteScore

3.0

Impact factor

1.7

ISSN

09599436 (Print)

1364551X (Electronic)

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