Synthesis and structure of sterically hindered o-benzoquinone carboxylic acid
2
Publication type: Journal Article
Publication date: 2021-03-31
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
2,4-Di-tert-butyl-5,6-dioxocyclohexa-1,3-diene-1-carboxylic acid, an oxidized analogue of sterically hindered pyrocatechuic acid, was obtained from 4,6-di-tert-butyl-2,3-dihydroxybenzaldehyde in four stages. The electrochemical reduction of this compound proceeds in two stages: the first reduction wave (Ered1 = −0.24 V) is irreversible, while the second stage is partially reversible (E1/2, red2 = −0.65 V). The molecular structure of the o-quinone carboxylic acid in the crystalline state was comfirmed by single-crystal X-ray analysis.
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Zherebtsov M. A. et al. Synthesis and structure of sterically hindered o-benzoquinone carboxylic acid // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 268-270.
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Zherebtsov M. A., Arsenyev M. V., Baranov E. V., Chesnokov S. A., Cherkasov V. K. Synthesis and structure of sterically hindered o-benzoquinone carboxylic acid // Mendeleev Communications. 2021. Vol. 31. No. 2. pp. 268-270.
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TY - JOUR
DO - 10.1016/j.mencom.2021.03.042
UR - https://doi.org/10.1016/j.mencom.2021.03.042
TI - Synthesis and structure of sterically hindered o-benzoquinone carboxylic acid
T2 - Mendeleev Communications
AU - Zherebtsov, Maxim A
AU - Arsenyev, Maxim V
AU - Baranov, Evgeny V
AU - Chesnokov, Sergey A.
AU - Cherkasov, Vladimir Kuzmich
PY - 2021
DA - 2021/03/31
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 268-270
IS - 2
VL - 31
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2021_Zherebtsov,
author = {Maxim A Zherebtsov and Maxim V Arsenyev and Evgeny V Baranov and Sergey A. Chesnokov and Vladimir Kuzmich Cherkasov},
title = {Synthesis and structure of sterically hindered o-benzoquinone carboxylic acid},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {mar},
url = {https://doi.org/10.1016/j.mencom.2021.03.042},
number = {2},
pages = {268--270},
doi = {10.1016/j.mencom.2021.03.042}
}
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Zherebtsov, Maxim A., et al. “Synthesis and structure of sterically hindered o-benzoquinone carboxylic acid.” Mendeleev Communications, vol. 31, no. 2, Mar. 2021, pp. 268-270. https://doi.org/10.1016/j.mencom.2021.03.042.