Mendeleev Communications

, том 31 , издание 4 , страницы 523-525

Alternative mechanistic interpretation for unconventional catalytic behaviour of triisobutylaluminium-activated heterocenes in ethylene polymerization

Ilya E. Nifant'ev ^{1, 2}

Alexander A Vinogradov ³

Alexey A. Vinogradov ³

Pavel V Ivchenko ^{1, 2}

Скрыть аффилиации авторов Показать аффилиации авторов: 3 аффилиации

A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991 Moscow, Russian Federation |

Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation |

A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 119991 Moscow, Russian Federation, |

Тип публикации: Journal Article

Дата публикации: 2021-07-01

OOO Zhurnal "Mendeleevskie Soobshcheniya"

Mendeleev Communications

scimago Q3

wos Q3

БС1

SJR: 0.305

CiteScore: 3.0

Impact factor: 1.7

ISSN: 09599436, 1364551X

DOI: 10.1016/j.mencom.2021.07.029

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General Chemistry

Краткое описание

DFT simulations of ethylene polymerization with the participation of neutral Zr–Al3 hydride species revealed a fundamental difference in catalytic behaviour of triisobutylaluminium-activated heterocenes and conventional ansa- zirconocenes.

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Polymer	Polymer, 1, 100% Polymer 1 публикация, 100%
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Nifant'ev I. E. et al. Alternative mechanistic interpretation for unconventional catalytic behaviour of triisobutylaluminium-activated heterocenes in ethylene polymerization // Mendeleev Communications. 2021. Vol. 31. No. 4. pp. 523-525.

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Nifant'ev I. E., Vinogradov A. A., Vinogradov A. A., Ivchenko P. V. Alternative mechanistic interpretation for unconventional catalytic behaviour of triisobutylaluminium-activated heterocenes in ethylene polymerization // Mendeleev Communications. 2021. Vol. 31. No. 4. pp. 523-525.

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TY - JOUR

DO - 10.1016/j.mencom.2021.07.029

UR - https://linkinghub.elsevier.com/retrieve/pii/S0959943621002030

TI - Alternative mechanistic interpretation for unconventional catalytic behaviour of triisobutylaluminium-activated heterocenes in ethylene polymerization

T2 - Mendeleev Communications

AU - Nifant'ev, Ilya E.

AU - Vinogradov, Alexander A

AU - Vinogradov, Alexey A.

AU - Ivchenko, Pavel V

PY - 2021

DA - 2021/07/01

PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"

SP - 523-525

IS - 4

VL - 31

SN - 0959-9436

SN - 1364-551X

ER -

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@article{2021_Nifant'ev,

author = {Ilya E. Nifant'ev and Alexander A Vinogradov and Alexey A. Vinogradov and Pavel V Ivchenko},

title = {Alternative mechanistic interpretation for unconventional catalytic behaviour of triisobutylaluminium-activated heterocenes in ethylene polymerization},

journal = {Mendeleev Communications},

year = {2021},

volume = {31},

publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},

month = {jul},

url = {https://linkinghub.elsevier.com/retrieve/pii/S0959943621002030},

number = {4},

pages = {523--525},

doi = {10.1016/j.mencom.2021.07.029}

}

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Nifant'ev, Ilya E., et al. “Alternative mechanistic interpretation for unconventional catalytic behaviour of triisobutylaluminium-activated heterocenes in ethylene polymerization.” Mendeleev Communications, vol. 31, no. 4, Jul. 2021, pp. 523-525. https://linkinghub.elsevier.com/retrieve/pii/S0959943621002030.