Nucleophilic ring opening of imidazolone activated donor–acceptor cyclopropanes with alcohols
Viktoria A Ikonnikova
1
,
Ekaterina A Zhigileva
1, 2
,
Andrei V Kuleshov
1, 2
,
Vasilissa V Shirokova
1
,
Mikhail Baranov
3
,
Andrey S. Mikhaylov
3
2
Publication type: Journal Article
Publication date: 2021-09-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
Imidazolone-activated donor–acceptor cyclopropanes undergo alcohol-assisted ring opening under the co-action of p -toluenesulfonic acid. Under the optimized conditions, cyclopropanes and alcohols are coupled in 1,3-fashion with the retention of heterocyclic fragment. Substrates with aromatic donor groups provide the addition products in 75–99% yields as mixtures of two diastereomers.
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Ikonnikova V. A. et al. Nucleophilic ring opening of imidazolone activated donor–acceptor cyclopropanes with alcohols // Mendeleev Communications. 2021. Vol. 31. No. 5. pp. 657-658.
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Ikonnikova V. A., Zhigileva E. A., Kuleshov A. V., Shirokova V. V., Baranov M., Mikhaylov A. S. Nucleophilic ring opening of imidazolone activated donor–acceptor cyclopropanes with alcohols // Mendeleev Communications. 2021. Vol. 31. No. 5. pp. 657-658.
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TY - JOUR
DO - 10.1016/j.mencom.2021.09.021
UR - https://doi.org/10.1016/j.mencom.2021.09.021
TI - Nucleophilic ring opening of imidazolone activated donor–acceptor cyclopropanes with alcohols
T2 - Mendeleev Communications
AU - Ikonnikova, Viktoria A
AU - Zhigileva, Ekaterina A
AU - Kuleshov, Andrei V
AU - Shirokova, Vasilissa V
AU - Baranov, Mikhail
AU - Mikhaylov, Andrey S.
PY - 2021
DA - 2021/09/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 657-658
IS - 5
VL - 31
SN - 0959-9436
SN - 1364-551X
ER -
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BibTex (up to 50 authors)
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@article{2021_Ikonnikova,
author = {Viktoria A Ikonnikova and Ekaterina A Zhigileva and Andrei V Kuleshov and Vasilissa V Shirokova and Mikhail Baranov and Andrey S. Mikhaylov},
title = {Nucleophilic ring opening of imidazolone activated donor–acceptor cyclopropanes with alcohols},
journal = {Mendeleev Communications},
year = {2021},
volume = {31},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {sep},
url = {https://doi.org/10.1016/j.mencom.2021.09.021},
number = {5},
pages = {657--658},
doi = {10.1016/j.mencom.2021.09.021}
}
Cite this
MLA
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Ikonnikova, Viktoria A., et al. “Nucleophilic ring opening of imidazolone activated donor–acceptor cyclopropanes with alcohols.” Mendeleev Communications, vol. 31, no. 5, Sep. 2021, pp. 657-658. https://doi.org/10.1016/j.mencom.2021.09.021.