, volume 31 , issue 6 , pages 804-806

Luminescent [Cu8I8L6] wheel and [Cu2I2L3] cage assembled from CuI and 3,6-bis(diphenylphosphino)pyridazine

Maxim I Rogovoy ¹

Mariana I. Rakhmanova ¹

Taisiya S. Sukhikh ¹

Alexander V. Artem'ev ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russian Federation |

Publication type: Journal Article

Publication date: 2021-11-01

OOO Zhurnal "Mendeleevskie Soobshcheniya"

Mendeleev Communications

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wos Q3

SJR: 0.305

CiteScore: 3.0

Impact factor: 1.7

ISSN: 09599436, 1364551X

DOI: 10.1016/j.mencom.2021.11.011

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General Chemistry

Abstract

The reaction of CuI and 3,6-bis(diphenylphosphino)pyridazine (dppz) in MeCN leads to the wheel-shaped complex [Cu 8 I 8 (dppz) 6 ], assembled from four [Cu 2 I 2 ] units and six dppz ligands. This complex exhibits thermochromic luminescence with emission colors ranging from red (300 K) to deep red (77 K). When carried out in the presence of PPh 3 , the reaction of CuI with dppz gives a non-emissive cage-like complex [Cu 2 I 2 (dppz) 3 ], in which two CuI units are P,P′-bridged by three dppz ligands.

Found

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Adonin Sergey

DSc in Chemistry, professor

201 publications, 3 037 citations, 22 reviews

h-index: 30

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

A.E. Favorsky Irkutsk Institute of Chemistry of the Siberian Branch of the Russian Academy of Sciences

South Ural State University

1 citation

Vinogradova Katerina

31 publications, 499 citations

h-index: 15

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

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Usoltsev Andrey

PhD in Chemistry

60 publications, 752 citations

h-index: 14

Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences

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Rogovoy M. I. et al. Luminescent [Cu8I8L6] wheel and [Cu2I2L3] cage assembled from CuI and 3,6-bis(diphenylphosphino)pyridazine // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 804-806.

GOST all authors (up to 50) Copy

Rogovoy M. I., Rakhmanova M. I., Sukhikh T. S., Artem'ev A. V. Luminescent [Cu8I8L6] wheel and [Cu2I2L3] cage assembled from CuI and 3,6-bis(diphenylphosphino)pyridazine // Mendeleev Communications. 2021. Vol. 31. No. 6. pp. 804-806.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.mencom.2021.11.011

UR - https://linkinghub.elsevier.com/retrieve/pii/S0959943621003035

TI - Luminescent [Cu8I8L6] wheel and [Cu2I2L3] cage assembled from CuI and 3,6-bis(diphenylphosphino)pyridazine

T2 - Mendeleev Communications

AU - Rogovoy, Maxim I

AU - Rakhmanova, Mariana I.

AU - Sukhikh, Taisiya S.

AU - Artem'ev, Alexander V.

PY - 2021

DA - 2021/11/01

PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"

SP - 804-806

IS - 6

VL - 31

SN - 0959-9436

SN - 1364-551X

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2021_Rogovoy,

author = {Maxim I Rogovoy and Mariana I. Rakhmanova and Taisiya S. Sukhikh and Alexander V. Artem'ev},

title = {Luminescent [Cu8I8L6] wheel and [Cu2I2L3] cage assembled from CuI and 3,6-bis(diphenylphosphino)pyridazine},

journal = {Mendeleev Communications},

year = {2021},

volume = {31},

publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},

month = {nov},

url = {https://linkinghub.elsevier.com/retrieve/pii/S0959943621003035},

number = {6},

pages = {804--806},

doi = {10.1016/j.mencom.2021.11.011}

}

MLA

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MLA Copy

Rogovoy, Maxim I., et al. “Luminescent [Cu8I8L6] wheel and [Cu2I2L3] cage assembled from CuI and 3,6-bis(diphenylphosphino)pyridazine.” Mendeleev Communications, vol. 31, no. 6, Nov. 2021, pp. 804-806. https://linkinghub.elsevier.com/retrieve/pii/S0959943621003035.