Hypercoordinate germanium complexes with phenanthrene-9,10-diolate ligands: synthesis, structure, and electronic properties
Publication type: Journal Article
Publication date: 2022-01-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
The synthesis, molecular structure, and electronic properties of sodium tris(phenanthrene-9,10-diolato)germanate(iv) are described. The germanate complex is readily oxidized in air to produce 9,10-phenanthrenequinone, and the resulting quinones and the ligands reveal intermolecular π-stacking interaction in the polymeric association in the solid state. Addition of phenanthroline to the germanate complex leads to a monomeric structure.
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Nanjo M., Yoneda T., Iwamatsu K. Hypercoordinate germanium complexes with phenanthrene-9,10-diolate ligands: synthesis, structure, and electronic properties // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 12-15.
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Nanjo M., Yoneda T., Iwamatsu K. Hypercoordinate germanium complexes with phenanthrene-9,10-diolate ligands: synthesis, structure, and electronic properties // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 12-15.
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TY - JOUR
DO - 10.1016/j.mencom.2022.01.003
UR - https://doi.org/10.1016/j.mencom.2022.01.003
TI - Hypercoordinate germanium complexes with phenanthrene-9,10-diolate ligands: synthesis, structure, and electronic properties
T2 - Mendeleev Communications
AU - Nanjo, M
AU - Yoneda, T
AU - Iwamatsu, K
PY - 2022
DA - 2022/01/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 12-15
IS - 1
VL - 32
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2022_Nanjo,
author = {M Nanjo and T Yoneda and K Iwamatsu},
title = {Hypercoordinate germanium complexes with phenanthrene-9,10-diolate ligands: synthesis, structure, and electronic properties},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jan},
url = {https://doi.org/10.1016/j.mencom.2022.01.003},
number = {1},
pages = {12--15},
doi = {10.1016/j.mencom.2022.01.003}
}
Cite this
MLA
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Nanjo, M., et al. “Hypercoordinate germanium complexes with phenanthrene-9,10-diolate ligands: synthesis, structure, and electronic properties.” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 12-15. https://doi.org/10.1016/j.mencom.2022.01.003.