Modification of bidentate bis(N-heterocyclic imine) ligands for low-valent main group complexes
Publication type: Journal Article
Publication date: 2022-01-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
The synthesis of modified neutral bis-NHI (NHI is N -heterocyclic imine) ligands and their application for the stabilization of tetryliumylidenes are reported. The ligands’ scaffolding consists of either saturated or methylated imidazoline backbones, and the bridge alternated from flexible ethylene to more rigid o -phenylene. Transmetalation reactivity of the cationic Sn II compounds was tested towards LiAlH 4 and IDipp→SiCl 2 [IDipp is 1,3-bis(2,6-diisopropyl- phenyl)imidazol-2-ylidene] affording the respective aluminium and silicon complexes.
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8
Total citations:
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Citations from 2025:
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(50%)
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GOST
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Hirmer S. V. et al. Modification of bidentate bis(N-heterocyclic imine) ligands for low-valent main group complexes // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 16-18.
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Hirmer S. V., Tschernuth F. S., Hanusch F., Baierl R., Muhr M., Inoue S. Modification of bidentate bis(N-heterocyclic imine) ligands for low-valent main group complexes // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 16-18.
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TY - JOUR
DO - 10.1016/j.mencom.2022.01.004
UR - https://doi.org/10.1016/j.mencom.2022.01.004
TI - Modification of bidentate bis(N-heterocyclic imine) ligands for low-valent main group complexes
T2 - Mendeleev Communications
AU - Hirmer, S V
AU - Tschernuth, F S
AU - Hanusch, F
AU - Baierl, R
AU - Muhr, M
AU - Inoue, S
PY - 2022
DA - 2022/01/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 16-18
IS - 1
VL - 32
SN - 0959-9436
SN - 1364-551X
ER -
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BibTex (up to 50 authors)
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@article{2022_Hirmer,
author = {S V Hirmer and F S Tschernuth and F Hanusch and R Baierl and M Muhr and S Inoue},
title = {Modification of bidentate bis(N-heterocyclic imine) ligands for low-valent main group complexes},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jan},
url = {https://doi.org/10.1016/j.mencom.2022.01.004},
number = {1},
pages = {16--18},
doi = {10.1016/j.mencom.2022.01.004}
}
Cite this
MLA
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Hirmer, S. V., et al. “Modification of bidentate bis(N-heterocyclic imine) ligands for low-valent main group complexes.” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 16-18. https://doi.org/10.1016/j.mencom.2022.01.004.