Improvement of the fluorescence quantum yield of triphenylene by the rotational effect of 4-(trimethylsilyl)phenyl groups
2
Yoyulabo Co., Ltd., Ota, Gunma 370-0313, Japan
|
Publication type: Journal Article
Publication date: 2022-01-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
The fluorescence quantum yield of triphenylene is low because the transition moment between the HOMOs and the LUMOs is negligibly small. To improve the fluorescence quantum yield, break of the symmetrical structure of triphenylene is necessary. We found that the rotational effect of the 4-(trimethylsilyl)phenyl groups of 2,3,6,7,10,11-hexakis[4-(trimethylsilyl)phenyl]triphenylene is effective to break the symmetry in spite of the symmetrical structure, leading to improvement of the fluorescence quantum yield.
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Kyushin S. et al. Improvement of the fluorescence quantum yield of triphenylene by the rotational effect of 4-(trimethylsilyl)phenyl groups // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 87-90.
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Kyushin S., Fujii H., NEGISHI K., Matsumoto H. Improvement of the fluorescence quantum yield of triphenylene by the rotational effect of 4-(trimethylsilyl)phenyl groups // Mendeleev Communications. 2022. Vol. 32. No. 1. pp. 87-90.
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TY - JOUR
DO - 10.1016/j.mencom.2022.01.028
UR - https://doi.org/10.1016/j.mencom.2022.01.028
TI - Improvement of the fluorescence quantum yield of triphenylene by the rotational effect of 4-(trimethylsilyl)phenyl groups
T2 - Mendeleev Communications
AU - Kyushin, Soichiro
AU - Fujii, Hidetoshi
AU - NEGISHI, Keisuke
AU - Matsumoto, Hideyuki
PY - 2022
DA - 2022/01/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 87-90
IS - 1
VL - 32
SN - 0959-9436
SN - 1364-551X
ER -
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BibTex (up to 50 authors)
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@article{2022_Kyushin,
author = {Soichiro Kyushin and Hidetoshi Fujii and Keisuke NEGISHI and Hideyuki Matsumoto},
title = {Improvement of the fluorescence quantum yield of triphenylene by the rotational effect of 4-(trimethylsilyl)phenyl groups},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jan},
url = {https://doi.org/10.1016/j.mencom.2022.01.028},
number = {1},
pages = {87--90},
doi = {10.1016/j.mencom.2022.01.028}
}
Cite this
MLA
Copy
Kyushin, Soichiro, et al. “Improvement of the fluorescence quantum yield of triphenylene by the rotational effect of 4-(trimethylsilyl)phenyl groups.” Mendeleev Communications, vol. 32, no. 1, Jan. 2022, pp. 87-90. https://doi.org/10.1016/j.mencom.2022.01.028.