Mendeleev Communications
,  volume 32 ,  issue 2 ,  pages 170-172

Gallium(iii)-mediated dimerization routes for (5-phenyl-2-thienyl)cyclopropane-1,1-dicarboxylate

Publication type: Journal Article
Publication date: 2022-03-31
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
A selectivity-switched dimerization process for (5-phenyl-2-thienyl)cyclopropane-1,1-dicarboxylate under activation conditions with anhydrous Gaiii salts was developed. Using GaCl3 or Ga(NTf2)3 as catalysts, 3a,4,5a,6,7,8-hexahydro-5H-pentaleno[6a,1-b]thiophene and 5,6-dihydro-4H-cyclo-penta[b]thiophene derivatives can be selectively obtained as a result of ipso-type and [3+2]-annulation type dimerization. The crucial role of a phenyl substituent at position 5 of the thiophene ring and some regularities are discussed.
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Borisov D. I., Novikov R. G., Tomilov Y. V. Gallium(iii)-mediated dimerization routes for (5-phenyl-2-thienyl)cyclopropane-1,1-dicarboxylate // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 170-172.
GOST all authors (up to 50) Copy
Borisov D. I., Novikov R. G., Tomilov Y. V. Gallium(iii)-mediated dimerization routes for (5-phenyl-2-thienyl)cyclopropane-1,1-dicarboxylate // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 170-172.
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TY - JOUR
DO - 10.1016/j.mencom.2022.03.005
UR - https://linkinghub.elsevier.com/retrieve/pii/S0959943622000700
TI - Gallium(iii)-mediated dimerization routes for (5-phenyl-2-thienyl)cyclopropane-1,1-dicarboxylate
T2 - Mendeleev Communications
AU - Borisov, D. I.
AU - Novikov, Roman G.
AU - Tomilov, Yury V.
PY - 2022
DA - 2022/03/31
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 170-172
IS - 2
VL - 32
SN - 0959-9436
SN - 1364-551X
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2022_Borisov,
author = {D. I. Borisov and Roman G. Novikov and Yury V. Tomilov},
title = {Gallium(iii)-mediated dimerization routes for (5-phenyl-2-thienyl)cyclopropane-1,1-dicarboxylate},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {mar},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0959943622000700},
number = {2},
pages = {170--172},
doi = {10.1016/j.mencom.2022.03.005}
}
MLA
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MLA Copy
Borisov, D. I., et al. “Gallium(iii)-mediated dimerization routes for (5-phenyl-2-thienyl)cyclopropane-1,1-dicarboxylate.” Mendeleev Communications, vol. 32, no. 2, Mar. 2022, pp. 170-172. https://linkinghub.elsevier.com/retrieve/pii/S0959943622000700.