Mendeleev Communications
,  volume 32 ,  issue 2 ,  pages 212-214

Synthesis, crystal structure and thermal properties of Na2Ti(CF3COO)6(CF3COOH)2

Publication type: Journal Article
Publication date: 2022-03-31
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
The compound Na 2 Ti(CF 3 COO) 6 (CF 3 COOH) 2 was synthesized as colorless crystals, extremely unstable in air, by the reaction of TiCl 4 with trifluoroacetic acid and sodium trifluoroacetate. Crystallographic studies have shown that this sodium trifluoroacetatotitanate is the first example of a tetravalent titanium carboxylate [Ti(RCOO) 6 ] 2 – containing titanium in an octahedral environment of oxygen atoms of carboxylate groups. Thermal decomposition of Na 2 Ti(CF 3 COO) 6 (CF 3 COOH) 2 in an argon atmosphere results in the complex fluoride Na 2 TiF 6 .
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GOST Copy
Buzoverov M. E. et al. Synthesis, crystal structure and thermal properties of Na2Ti(CF3COO)6(CF3COOH)2 // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 212-214.
GOST all authors (up to 50) Copy
Buzoverov M. E., Glazunova T. Y., Lermontova E. K. Synthesis, crystal structure and thermal properties of Na2Ti(CF3COO)6(CF3COOH)2 // Mendeleev Communications. 2022. Vol. 32. No. 2. pp. 212-214.
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RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2022.03.019
UR - https://linkinghub.elsevier.com/retrieve/pii/S0959943622000840
TI - Synthesis, crystal structure and thermal properties of Na2Ti(CF3COO)6(CF3COOH)2
T2 - Mendeleev Communications
AU - Buzoverov, Mikhail E
AU - Glazunova, Tatyana Yu.
AU - Lermontova, Elmira Kh.
PY - 2022
DA - 2022/03/31
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 212-214
IS - 2
VL - 32
SN - 0959-9436
SN - 1364-551X
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2022_Buzoverov,
author = {Mikhail E Buzoverov and Tatyana Yu. Glazunova and Elmira Kh. Lermontova},
title = {Synthesis, crystal structure and thermal properties of Na2Ti(CF3COO)6(CF3COOH)2},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {mar},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0959943622000840},
number = {2},
pages = {212--214},
doi = {10.1016/j.mencom.2022.03.019}
}
MLA
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MLA Copy
Buzoverov, Mikhail E., et al. “Synthesis, crystal structure and thermal properties of Na2Ti(CF3COO)6(CF3COOH)2.” Mendeleev Communications, vol. 32, no. 2, Mar. 2022, pp. 212-214. https://linkinghub.elsevier.com/retrieve/pii/S0959943622000840.