Unusual reactivity of tantalum pentakis(dimethylpyrazolate) with CS2: scission of the C=S bond and formation of dmpz3CS– ligand
Publication type: Journal Article
Publication date: 2022-09-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
The reaction beetwen tantalum pentakis(3,5-dimethyl-pyrazolate) and CS 2 afforded novel complex [Ta(=S)(dmpz) 2 {(dmpz) 3 CS}]. In this reaction the molecule of CS 2 undergoes scission with the migration of one sulfide to the tantalum atom while three pyrazolate residues migrate to carbon with the formation of unusual (dmpz) 3 CS – ligand. The structure of the product was established by X-ray diffraction.
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Petrov P. A. et al. Unusual reactivity of tantalum pentakis(dimethylpyrazolate) with CS2: scission of the C=S bond and formation of dmpz3CS– ligand // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 579-581.
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Petrov P. A., Jiang X., Sukhikh T. S., Eltsov I. V., Abramov P. A., Sokolov M. N. Unusual reactivity of tantalum pentakis(dimethylpyrazolate) with CS2: scission of the C=S bond and formation of dmpz3CS– ligand // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 579-581.
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TY - JOUR
DO - 10.1016/j.mencom.2022.09.003
UR - https://doi.org/10.1016/j.mencom.2022.09.003
TI - Unusual reactivity of tantalum pentakis(dimethylpyrazolate) with CS2: scission of the C=S bond and formation of dmpz3CS– ligand
T2 - Mendeleev Communications
AU - Petrov, Pavel A.
AU - Jiang, Xiaohong
AU - Sukhikh, Taisiya S.
AU - Eltsov, Ilia V.
AU - Abramov, Pavel A.
AU - Sokolov, Maxim N.
PY - 2022
DA - 2022/09/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 579-581
IS - 5
VL - 32
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2022_Petrov,
author = {Pavel A. Petrov and Xiaohong Jiang and Taisiya S. Sukhikh and Ilia V. Eltsov and Pavel A. Abramov and Maxim N. Sokolov},
title = {Unusual reactivity of tantalum pentakis(dimethylpyrazolate) with CS2: scission of the C=S bond and formation of dmpz3CS– ligand},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {sep},
url = {https://doi.org/10.1016/j.mencom.2022.09.003},
number = {5},
pages = {579--581},
doi = {10.1016/j.mencom.2022.09.003}
}
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MLA
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Petrov, Pavel A., et al. “Unusual reactivity of tantalum pentakis(dimethylpyrazolate) with CS2: scission of the C=S bond and formation of dmpz3CS– ligand.” Mendeleev Communications, vol. 32, no. 5, Sep. 2022, pp. 579-581. https://doi.org/10.1016/j.mencom.2022.09.003.