Structure of novel N-fluorosilylmethyl-N-isopropylureas
Publication type: Journal Article
Publication date: 2022-09-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
Novel N -isopropyl- N' , N' -dimethyl- N -(silylmethyl)ureas Me 2 NC(O)N(Pr i )CH 2 SiMe n X 3– n (X = OEt, F; n = 0–2) were synthesized, and their structure was confirmed by 1 H, 13 C and 29 Si NMR spectroscopy. According to NMR data, the silicon atom of the fluorosilanes (X = F) is pentacoordinated. The X-ray diffraction analysis of the (trifluorosilyl)methylcontaining urea showed that it exists as (O–Si) chelate with intramolecular dative bond C=O→Si (1.880 Å).
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Total citations:
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Citations from 2025:
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Lazareva N. B., Alekseev M. A., Sterkhova I. Structure of novel N-fluorosilylmethyl-N-isopropylureas // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 686-687.
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Lazareva N. B., Alekseev M. A., Sterkhova I. Structure of novel N-fluorosilylmethyl-N-isopropylureas // Mendeleev Communications. 2022. Vol. 32. No. 5. pp. 686-687.
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TY - JOUR
DO - 10.1016/j.mencom.2022.09.040
UR - https://doi.org/10.1016/j.mencom.2022.09.040
TI - Structure of novel N-fluorosilylmethyl-N-isopropylureas
T2 - Mendeleev Communications
AU - Lazareva, Natalya B.
AU - Alekseev, Mikhail A.
AU - Sterkhova, Irina
PY - 2022
DA - 2022/09/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 686-687
IS - 5
VL - 32
SN - 0959-9436
SN - 1364-551X
ER -
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BibTex (up to 50 authors)
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@article{2022_Lazareva,
author = {Natalya B. Lazareva and Mikhail A. Alekseev and Irina Sterkhova},
title = {Structure of novel N-fluorosilylmethyl-N-isopropylureas},
journal = {Mendeleev Communications},
year = {2022},
volume = {32},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {sep},
url = {https://doi.org/10.1016/j.mencom.2022.09.040},
number = {5},
pages = {686--687},
doi = {10.1016/j.mencom.2022.09.040}
}
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MLA
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Lazareva, Natalya B., et al. “Structure of novel N-fluorosilylmethyl-N-isopropylureas.” Mendeleev Communications, vol. 32, no. 5, Sep. 2022, pp. 686-687. https://doi.org/10.1016/j.mencom.2022.09.040.