Open Access
Effect of stereocomplex formation between enantiomeric poly(l,l-lactide) and poly(d,d-lactide) blocks on self-organization of amphiphilic poly(lactide)-block-poly(ethylene oxide) copolymers in dilute aqueous solution
Anastasiia M. Desyatskova
1
,
Yulia A. Puchkova
1, 2
,
Evgeny V. Yastremsky
1, 3
,
A. V. Bakirov
1, 2
,
Alexander I Buzin
2
,
S. N. Chvalun
1, 2
Publication type: Journal Article
Publication date: 2023-01-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
The effect of crystallization of a hydrophobic poly(lactide) block on the self-organization of biocompatible and biodegradable amphiphilic poly(lactide)-block-poly(ethylene oxide) (PLA-b-PEO) copolymers in a dilute aqueous solution has been investigated. It was demonstrated that the co-crystallization of poly(L,L-lactide) [P(L,L)LA] and poly(d,d-lactide) [P(d,d)LA] chains under equimolar mixing of P(L,L)LA46-b-PEO113 and P(d,d)LA56-b-PEO113 copolymers resulted in the formation of stable and spontaneously water-redispersible stereocomplex micelles with semicrystalline P(L,L)LA/P(d,d)LA cores. It was shown that the P(L,L)LA46 / P(d,d)LA56-b-PEO113 stereo-complex micelles produced by dialysis can be potential vehicles for the anticancer agent oxaliplatin
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Total citations:
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Citations from 2025:
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Desyatskova A. M. et al. Effect of stereocomplex formation between enantiomeric poly(l,l-lactide) and poly(d,d-lactide) blocks on self-organization of amphiphilic poly(lactide)-block-poly(ethylene oxide) copolymers in dilute aqueous solution // Mendeleev Communications. 2023. Vol. 33. No. 1. pp. 86-89.
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Desyatskova A. M., Kuznetsova E. V., Puchkova Y. A., Yastremsky E. V., Bakirov A. V., Dmitryakov P. V., Buzin A. I., Chvalun S. N. Effect of stereocomplex formation between enantiomeric poly(l,l-lactide) and poly(d,d-lactide) blocks on self-organization of amphiphilic poly(lactide)-block-poly(ethylene oxide) copolymers in dilute aqueous solution // Mendeleev Communications. 2023. Vol. 33. No. 1. pp. 86-89.
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TY - JOUR
DO - 10.1016/j.mencom.2023.01.027
UR - https://doi.org/10.1016/j.mencom.2023.01.027
TI - Effect of stereocomplex formation between enantiomeric poly(l,l-lactide) and poly(d,d-lactide) blocks on self-organization of amphiphilic poly(lactide)-block-poly(ethylene oxide) copolymers in dilute aqueous solution
T2 - Mendeleev Communications
AU - Desyatskova, Anastasiia M.
AU - Kuznetsova, Ekaterina V.
AU - Puchkova, Yulia A.
AU - Yastremsky, Evgeny V.
AU - Bakirov, A. V.
AU - Dmitryakov, Petr V.
AU - Buzin, Alexander I
AU - Chvalun, S. N.
PY - 2023
DA - 2023/01/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 86-89
IS - 1
VL - 33
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2023_Desyatskova,
author = {Anastasiia M. Desyatskova and Ekaterina V. Kuznetsova and Yulia A. Puchkova and Evgeny V. Yastremsky and A. V. Bakirov and Petr V. Dmitryakov and Alexander I Buzin and S. N. Chvalun},
title = {Effect of stereocomplex formation between enantiomeric poly(l,l-lactide) and poly(d,d-lactide) blocks on self-organization of amphiphilic poly(lactide)-block-poly(ethylene oxide) copolymers in dilute aqueous solution},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jan},
url = {https://doi.org/10.1016/j.mencom.2023.01.027},
number = {1},
pages = {86--89},
doi = {10.1016/j.mencom.2023.01.027}
}
Cite this
MLA
Copy
Desyatskova, Anastasiia M., et al. “Effect of stereocomplex formation between enantiomeric poly(l,l-lactide) and poly(d,d-lactide) blocks on self-organization of amphiphilic poly(lactide)-block-poly(ethylene oxide) copolymers in dilute aqueous solution.” Mendeleev Communications, vol. 33, no. 1, Jan. 2023, pp. 86-89. https://doi.org/10.1016/j.mencom.2023.01.027.