Mendeleev Communications
,  volume 33 ,  issue 2 ,  pages 180-183

A pyridine promoted ‘weak base route’ to (NHC)2NiCl2 complexes with bulky N,N'-diaryl carbene ligands

Publication type: Journal Article
Publication date: 2023-03-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
A simple one-step synthesis of (NHC)2NiCl2 complexes containing bulky N-heterocyclic carbene (NHC) ligands relies on the C–H metallation of N,N'-diaryl-substituted azolium salts, NHC-precursors, with NiCl2Py2 in the presence of Cs2CO3 and pyridine. This procedure allows one to implement all synthetic manipulations in air.
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Khazipov O. V. et al. A pyridine promoted ‘weak base route’ to (NHC)2NiCl2 complexes with bulky N,N'-diaryl carbene ligands // Mendeleev Communications. 2023. Vol. 33. No. 2. pp. 180-183.
GOST all authors (up to 50) Copy
Khazipov O. V., Pyatachenko A. S., Pasyukov D. V., Minyaev M. E., Chernyshev V. M. A pyridine promoted ‘weak base route’ to (NHC)2NiCl2 complexes with bulky N,N'-diaryl carbene ligands // Mendeleev Communications. 2023. Vol. 33. No. 2. pp. 180-183.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2023.02.010
UR - https://doi.org/10.1016/j.mencom.2023.02.010
TI - A pyridine promoted ‘weak base route’ to (NHC)2NiCl2 complexes with bulky N,N'-diaryl carbene ligands
T2 - Mendeleev Communications
AU - Khazipov, Oleg V
AU - Pyatachenko, Anastasia S.
AU - Pasyukov, Dmitry V
AU - Minyaev, Mikhail E.
AU - Chernyshev, Victor M.
PY - 2023
DA - 2023/03/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 180-183
IS - 2
VL - 33
SN - 0959-9436
SN - 1364-551X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2023_Khazipov,
author = {Oleg V Khazipov and Anastasia S. Pyatachenko and Dmitry V Pasyukov and Mikhail E. Minyaev and Victor M. Chernyshev},
title = {A pyridine promoted ‘weak base route’ to (NHC)2NiCl2 complexes with bulky N,N'-diaryl carbene ligands},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {mar},
url = {https://doi.org/10.1016/j.mencom.2023.02.010},
number = {2},
pages = {180--183},
doi = {10.1016/j.mencom.2023.02.010}
}
MLA
Cite this
MLA Copy
Khazipov, Oleg V., et al. “A pyridine promoted ‘weak base route’ to (NHC)2NiCl2 complexes with bulky N,N'-diaryl carbene ligands.” Mendeleev Communications, vol. 33, no. 2, Mar. 2023, pp. 180-183. https://doi.org/10.1016/j.mencom.2023.02.010.