Titanium dioxide nanoparticles heavily doped with niobium: A light-induced electron paramagnetic resonance study
Vladimir Osipov
1, 2
,
Dong Hao
3, 4
,
KAZUYUKI TAKAI
1
,
Tetsuo Uchikoshi
4, 5
,
Hironori Ogata
1, 4
,
Takamasa Ishigaki
1, 4
Publication type: Journal Article
Publication date: 2023-05-19
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
Light-induced electron paramagnetic resonance (EPR) spectra of titanium dioxide nanoparticles heavily doped with niobium(v) are studied. At low temperatures, the EPR signal caused by interband illumination is associated with paramagnetic Ti3+ sites in anatase, which, as the temperature rises above 210 K, are discharged to the non-paramagnetic Ti4+ state due to the escape of trapped photoelectrons and their recombination with holes. The temperature dependence of the integral EPR signal has a non-Curie character, especially in the temperature range where the discharge of Ti3+ centers is already significant.
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Osipov V. et al. Titanium dioxide nanoparticles heavily doped with niobium: A light-induced electron paramagnetic resonance study // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 349-352.
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Osipov V., Hao D., TAKAI K., Uchikoshi T., Ogata H., Ishigaki T. Titanium dioxide nanoparticles heavily doped with niobium: A light-induced electron paramagnetic resonance study // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 349-352.
Cite this
RIS
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TY - JOUR
DO - 10.1016/j.mencom.2023.04.017
UR - https://doi.org/10.1016/j.mencom.2023.04.017
TI - Titanium dioxide nanoparticles heavily doped with niobium: A light-induced electron paramagnetic resonance study
T2 - Mendeleev Communications
AU - Osipov, Vladimir
AU - Hao, Dong
AU - TAKAI, KAZUYUKI
AU - Uchikoshi, Tetsuo
AU - Ogata, Hironori
AU - Ishigaki, Takamasa
PY - 2023
DA - 2023/05/19
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 349-352
IS - 3
VL - 33
SN - 0959-9436
SN - 1364-551X
ER -
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BibTex (up to 50 authors)
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@article{2023_Osipov,
author = {Vladimir Osipov and Dong Hao and KAZUYUKI TAKAI and Tetsuo Uchikoshi and Hironori Ogata and Takamasa Ishigaki},
title = {Titanium dioxide nanoparticles heavily doped with niobium: A light-induced electron paramagnetic resonance study},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {may},
url = {https://doi.org/10.1016/j.mencom.2023.04.017},
number = {3},
pages = {349--352},
doi = {10.1016/j.mencom.2023.04.017}
}
Cite this
MLA
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Osipov, Vladimir, et al. “Titanium dioxide nanoparticles heavily doped with niobium: A light-induced electron paramagnetic resonance study.” Mendeleev Communications, vol. 33, no. 3, May. 2023, pp. 349-352. https://doi.org/10.1016/j.mencom.2023.04.017.