Photoinduced recoordination in the complexes of bis-aza-18-crown-6-containing dibenzylidenecyclobutanone with alkali and alkaline-earth metal cations
Mikhail N Khimich
1
,
Mikhail Ya Melnikov
1
,
Anton E Egorov
2
,
Roman O Starostin
1, 3
,
Marina V. Fomina
3
,
Sergey P Gromov
1, 3
1
Publication type: Journal Article
Publication date: 2023-05-19
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
Complexation with strong competitors (i.e., Ba2+, Ca2+, and K+) shortens the length of the chromophore in bis-aza-18-crown-6-containing dienones of 2,4-dibenzylenecyclo-butanone series due to the weakening of π–LP conjugation as well as disruption of the quinonoid structure in the ground state of the dye (LP is the lone electron pair of the crown nitrogen atom). In the excited state, recoordination of metal cations in the crown cavity takes place. The complexation as well as the newly discovered photorecoordination in these metal complexes may be used to control the chromophore properties of the samples.
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Volchkov V. V. et al. Photoinduced recoordination in the complexes of bis-aza-18-crown-6-containing dibenzylidenecyclobutanone with alkali and alkaline-earth metal cations // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 380-383.
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Volchkov V. V., Khimich M. N., Melnikov M. Ya., Egorov A. E., Starostin R. O., Fomina M. V., Gromov S. P. Photoinduced recoordination in the complexes of bis-aza-18-crown-6-containing dibenzylidenecyclobutanone with alkali and alkaline-earth metal cations // Mendeleev Communications. 2023. Vol. 33. No. 3. pp. 380-383.
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TY - JOUR
DO - 10.1016/j.mencom.2023.04.026
UR - https://linkinghub.elsevier.com/retrieve/pii/S0959943623001426
TI - Photoinduced recoordination in the complexes of bis-aza-18-crown-6-containing dibenzylidenecyclobutanone with alkali and alkaline-earth metal cations
T2 - Mendeleev Communications
AU - Volchkov, Valery V
AU - Khimich, Mikhail N
AU - Melnikov, Mikhail Ya
AU - Egorov, Anton E
AU - Starostin, Roman O
AU - Fomina, Marina V.
AU - Gromov, Sergey P
PY - 2023
DA - 2023/05/19
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 380-383
IS - 3
VL - 33
SN - 0959-9436
SN - 1364-551X
ER -
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BibTex (up to 50 authors)
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@article{2023_Volchkov,
author = {Valery V Volchkov and Mikhail N Khimich and Mikhail Ya Melnikov and Anton E Egorov and Roman O Starostin and Marina V. Fomina and Sergey P Gromov},
title = {Photoinduced recoordination in the complexes of bis-aza-18-crown-6-containing dibenzylidenecyclobutanone with alkali and alkaline-earth metal cations},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {may},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0959943623001426},
number = {3},
pages = {380--383},
doi = {10.1016/j.mencom.2023.04.026}
}
Cite this
MLA
Copy
Volchkov, Valery V., et al. “Photoinduced recoordination in the complexes of bis-aza-18-crown-6-containing dibenzylidenecyclobutanone with alkali and alkaline-earth metal cations.” Mendeleev Communications, vol. 33, no. 3, May. 2023, pp. 380-383. https://linkinghub.elsevier.com/retrieve/pii/S0959943623001426.