Weak ferromagnetism in a diamagnetically diluted sublattice of Fe3+ ions in solid solutions Y2 − Fe1 + TaO7 (x = 0 –0.2) with pyrochlore-like structure
Anna V. Egorysheva
1
,
Olga G Ellert
1
,
Elena F. Popova
1
,
Denis I. Kirdyankin
1
,
Yuri V Maksimov
2
Publication type: Journal Article
Publication date: 2023-07-17
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
A series of layered solid solutions Y2-xFe1+xTaO7 (x = 0–0.2) was synthesized and a structural transition (space group R3¯ ↔ space group P3121) was observed at x = 0.1. In Y2−xFe1+xTaO7, which belongs to both structural types, geometrically frustrated 2D sublattices of kagome-type are formed, in which Fe3+ ions are coupled by short-range antiferromagnetic interactions, and the transition to the spin glass state is observed at Tg ∼ 4.3 K. A phenomenon of weak ferromagnetism has been detected, the cause of which is probably a small tilt of the Fe3+ spins due to the Dzyaloshinskii–Moriya antisymmetric superexchange.
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Egorysheva A. V. et al. Weak ferromagnetism in a diamagnetically diluted sublattice of Fe3+ ions in solid solutions Y2 − Fe1 + TaO7 (x = 0 –0.2) with pyrochlore-like structure // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 519-521.
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Egorysheva A. V., Ellert O. G., Popova E. F., Kirdyankin D. I., Maksimov Y. V. Weak ferromagnetism in a diamagnetically diluted sublattice of Fe3+ ions in solid solutions Y2 − Fe1 + TaO7 (x = 0 –0.2) with pyrochlore-like structure // Mendeleev Communications. 2023. Vol. 33. No. 4. pp. 519-521.
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TY - JOUR
DO - 10.1016/j.mencom.2023.06.025
UR - https://doi.org/10.1016/j.mencom.2023.06.025
TI - Weak ferromagnetism in a diamagnetically diluted sublattice of Fe3+ ions in solid solutions Y2 − Fe1 + TaO7 (x = 0 –0.2) with pyrochlore-like structure
T2 - Mendeleev Communications
AU - Egorysheva, Anna V.
AU - Ellert, Olga G
AU - Popova, Elena F.
AU - Kirdyankin, Denis I.
AU - Maksimov, Yuri V
PY - 2023
DA - 2023/07/17
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 519-521
IS - 4
VL - 33
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2023_Egorysheva,
author = {Anna V. Egorysheva and Olga G Ellert and Elena F. Popova and Denis I. Kirdyankin and Yuri V Maksimov},
title = {Weak ferromagnetism in a diamagnetically diluted sublattice of Fe3+ ions in solid solutions Y2 − Fe1 + TaO7 (x = 0 –0.2) with pyrochlore-like structure},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jul},
url = {https://doi.org/10.1016/j.mencom.2023.06.025},
number = {4},
pages = {519--521},
doi = {10.1016/j.mencom.2023.06.025}
}
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MLA
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Egorysheva, Anna V., et al. “Weak ferromagnetism in a diamagnetically diluted sublattice of Fe3+ ions in solid solutions Y2 − Fe1 + TaO7 (x = 0 –0.2) with pyrochlore-like structure.” Mendeleev Communications, vol. 33, no. 4, Jul. 2023, pp. 519-521. https://doi.org/10.1016/j.mencom.2023.06.025.
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