Mendeleev Communications
,  volume 33 ,  issue 5 ,  pages 708-710

Unexpected hydrazine- and hydroxylamine-induced transformations of aza-14-crown-4 incorporating 4-oxopiperidine-3-carboxylate moiety

Dat Nguyen 1
, 
Hieu H Truong 2
, 
Nhung Thi Dao 1
, 
Van Tran 1
, 
Olga S. Gorchakova 3
, 
Duc Anh Le 1
1
 
2
 
3
 
‘Sanofi-aventis group’ Representative office in Russia, 125009, Moscow, Russian Federation | 
Publication type: Journal Article
Publication date: 2023-09-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
Reactions of aza-14-crown-4 incorporating 4-oxopiperidine-3-carboxylate moiety with hydrazine and hydroxylamine proceed at the functional groups. One unexpected product, cyclopenteno-13-crown-3 ether derivative, is formed when hydrazine hydrochloride is used, its formation occurring via deamination of the piperidine followed by the Nazarov reaction of the intermediate hydrazono diene. According to the QSAR through ADMET calculation, the synthesized compounds may show high potential for biological studies.
Found 
Found 

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GOST |
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GOST Copy
Nguyen D. et al. Unexpected hydrazine- and hydroxylamine-induced transformations of aza-14-crown-4 incorporating 4-oxopiperidine-3-carboxylate moiety // Mendeleev Communications. 2023. Vol. 33. No. 5. pp. 708-710.
GOST all authors (up to 50) Copy
Nguyen D., Truong H. H., Dao N. T., Tran V., Gorchakova O. S., Le D. A. Unexpected hydrazine- and hydroxylamine-induced transformations of aza-14-crown-4 incorporating 4-oxopiperidine-3-carboxylate moiety // Mendeleev Communications. 2023. Vol. 33. No. 5. pp. 708-710.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2023.09.037
UR - https://doi.org/10.1016/j.mencom.2023.09.037
TI - Unexpected hydrazine- and hydroxylamine-induced transformations of aza-14-crown-4 incorporating 4-oxopiperidine-3-carboxylate moiety
T2 - Mendeleev Communications
AU - Nguyen, Dat
AU - Truong, Hieu H
AU - Dao, Nhung Thi
AU - Tran, Van
AU - Gorchakova, Olga S.
AU - Le, Duc Anh
PY - 2023
DA - 2023/09/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 708-710
IS - 5
VL - 33
SN - 0959-9436
SN - 1364-551X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2023_Nguyen,
author = {Dat Nguyen and Hieu H Truong and Nhung Thi Dao and Van Tran and Olga S. Gorchakova and Duc Anh Le},
title = {Unexpected hydrazine- and hydroxylamine-induced transformations of aza-14-crown-4 incorporating 4-oxopiperidine-3-carboxylate moiety},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {sep},
url = {https://doi.org/10.1016/j.mencom.2023.09.037},
number = {5},
pages = {708--710},
doi = {10.1016/j.mencom.2023.09.037}
}
MLA
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MLA Copy
Nguyen, Dat, et al. “Unexpected hydrazine- and hydroxylamine-induced transformations of aza-14-crown-4 incorporating 4-oxopiperidine-3-carboxylate moiety.” Mendeleev Communications, vol. 33, no. 5, Sep. 2023, pp. 708-710. https://doi.org/10.1016/j.mencom.2023.09.037.
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