One-pot synthesis of perfluorinated benzenedithiols from perfluoroarenes and thioacetic acid
Publication type: Journal Article
Publication date: 2023-09-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
The direction of the reaction between substituted perfluorobenzenes and thioacetic acid depends on the location of the substituents in perfluoroaromatic ring. Hexafluorobenzene reacts at positions 1 and 4, perfluoro-m-xylene reacts at positions 4 and 6, while perfluoroindane reacts at positions 5 and 6 to give the corresponding dithiols with para-, meta- and ortho-location of the thiol groups, respectively. Domino-reaction of perfluoroindane-5-thiol and its acetyl thioester affords hexadecafluoro-2,12-dithia-pentacyclo[11.7.0.03,11.05,9.015,19]icosa-1(13),3,5(9),10,14,19-hexaene
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Nikulshin P. V. et al. One-pot synthesis of perfluorinated benzenedithiols from perfluoroarenes and thioacetic acid // Mendeleev Communications. 2023. Vol. 33. No. 5. pp. 721-722.
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Nikulshin P. V., Maksimov A., Gatilov Y. V., Kovtonyuk V. N., Bredikhin R. A. One-pot synthesis of perfluorinated benzenedithiols from perfluoroarenes and thioacetic acid // Mendeleev Communications. 2023. Vol. 33. No. 5. pp. 721-722.
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TY - JOUR
DO - 10.1016/j.mencom.2023.09.041
UR - https://doi.org/10.1016/j.mencom.2023.09.041
TI - One-pot synthesis of perfluorinated benzenedithiols from perfluoroarenes and thioacetic acid
T2 - Mendeleev Communications
AU - Nikulshin, P V
AU - Maksimov, A.
AU - Gatilov, Yuriy V.
AU - Kovtonyuk, Vladimir N
AU - Bredikhin, R A
PY - 2023
DA - 2023/09/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 721-722
IS - 5
VL - 33
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2023_Nikulshin,
author = {P V Nikulshin and A. Maksimov and Yuriy V. Gatilov and Vladimir N Kovtonyuk and R A Bredikhin},
title = {One-pot synthesis of perfluorinated benzenedithiols from perfluoroarenes and thioacetic acid},
journal = {Mendeleev Communications},
year = {2023},
volume = {33},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {sep},
url = {https://doi.org/10.1016/j.mencom.2023.09.041},
number = {5},
pages = {721--722},
doi = {10.1016/j.mencom.2023.09.041}
}
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Nikulshin, P. V., et al. “One-pot synthesis of perfluorinated benzenedithiols from perfluoroarenes and thioacetic acid.” Mendeleev Communications, vol. 33, no. 5, Sep. 2023, pp. 721-722. https://doi.org/10.1016/j.mencom.2023.09.041.
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