Active Pd species in the formation of polysubstituted olefins and naphthalenes in the reaction between arylboronic acid and diphenylacetylene
Publication type: Journal Article
Publication date: 2024-03-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
'Ligand-free' Pd-catalyzed reaction between arylboronic acid and diphenylacetylene affords a set of polyphenylated olefins and 1,2,3,4-tetraphenylnaphthalene whose yields are dependent on counteranion of PdII salt and additive nature. Tetraphenylethylene and hexaphenylbuta-1,3-diene are likely formed in tandem arylation/cross-coupling reaction with the participation of hydroxo/alkoxo alkenyl Pd species, whereas 1,2,3,4-tetraphenylnaphthalene formation probably proceeds through tandem arylation/C–H activation by halide-containing alkenyl Pd complexes.
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Schmidt A. F. et al. Active Pd species in the formation of polysubstituted olefins and naphthalenes in the reaction between arylboronic acid and diphenylacetylene // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 215-217.
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Schmidt A. F., Larina E. V., Lagoda N. A., Schmidt A. F. Active Pd species in the formation of polysubstituted olefins and naphthalenes in the reaction between arylboronic acid and diphenylacetylene // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 215-217.
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TY - JOUR
DO - 10.1016/j.mencom.2024.02.018
UR - https://linkinghub.elsevier.com/retrieve/pii/S0959943624000762
TI - Active Pd species in the formation of polysubstituted olefins and naphthalenes in the reaction between arylboronic acid and diphenylacetylene
T2 - Mendeleev Communications
AU - Schmidt, Alexander F
AU - Larina, Elizaveta V.
AU - Lagoda, Nadezhda A.
AU - Schmidt, Alexander F
PY - 2024
DA - 2024/03/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 215-217
IS - 2
VL - 34
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2024_Schmidt,
author = {Alexander F Schmidt and Elizaveta V. Larina and Nadezhda A. Lagoda and Alexander F Schmidt},
title = {Active Pd species in the formation of polysubstituted olefins and naphthalenes in the reaction between arylboronic acid and diphenylacetylene},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {mar},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0959943624000762},
number = {2},
pages = {215--217},
doi = {10.1016/j.mencom.2024.02.018}
}
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MLA
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Schmidt, Alexander F., et al. “Active Pd species in the formation of polysubstituted olefins and naphthalenes in the reaction between arylboronic acid and diphenylacetylene.” Mendeleev Communications, vol. 34, no. 2, Mar. 2024, pp. 215-217. https://linkinghub.elsevier.com/retrieve/pii/S0959943624000762.
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