Mendeleev Communications
,  volume 34 ,  issue 2 ,  pages 242-245

Low-temperature synthesis in the dittmarite–sodium acetate trihydrate system: electrochemical activity of M3+/M2+ redox couples in AMPO4 (A = Na, Li; M = Mn, Mn/Fe)

Publication type: Journal Article
Publication date: 2024-03-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
Phase-pure NaMPO4 (M = Mn, Mn/Fe; isotypic to triphylite) and Li(Mn/Fe)PO4 were isolated as a result of the low- temperature reaction between NH4MPO4·H2O (M = Mn, Mn/Fe) and AcONa·3H2O or AcOLi, respectively. Electrochemical tests in half-cells revealed that Na-based compounds exhibit poor electrochemical activity vs. metallic Na, while the similarly synthesized Li counterpart demonstrates decent cycling in Na cells. The synthetic features, crystal structures and properties of related members of the olivine family are discussed.
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Samarin A. S. et al. Low-temperature synthesis in the dittmarite–sodium acetate trihydrate system: electrochemical activity of M3+/M2+ redox couples in AMPO4 (A = Na, Li; M = Mn, Mn/Fe) // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 242-245.
GOST all authors (up to 50) Copy
Samarin A. S., Ivanova T. V., Ivanova T., Nazarov E. E., Marshenya S. N., Luchinin N. D., Antipov E. V., Fedotov S. S. Low-temperature synthesis in the dittmarite–sodium acetate trihydrate system: electrochemical activity of M3+/M2+ redox couples in AMPO4 (A = Na, Li; M = Mn, Mn/Fe) // Mendeleev Communications. 2024. Vol. 34. No. 2. pp. 242-245.
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RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2024.02.027
UR - https://linkinghub.elsevier.com/retrieve/pii/S0959943624000853
TI - Low-temperature synthesis in the dittmarite–sodium acetate trihydrate system: electrochemical activity of M3+/M2+ redox couples in AMPO4 (A = Na, Li; M = Mn, Mn/Fe)
T2 - Mendeleev Communications
AU - Samarin, Aleksandr Sh
AU - Ivanova, Tatiana V.
AU - Ivanova, T.
AU - Nazarov, Eugene E.
AU - Marshenya, Sergey N.
AU - Luchinin, Nikita D
AU - Antipov, Evgeny V.
AU - Fedotov, Stanislav S.
PY - 2024
DA - 2024/03/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 242-245
IS - 2
VL - 34
SN - 0959-9436
SN - 1364-551X
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2024_Samarin,
author = {Aleksandr Sh Samarin and Tatiana V. Ivanova and T. Ivanova and Eugene E. Nazarov and Sergey N. Marshenya and Nikita D Luchinin and Evgeny V. Antipov and Stanislav S. Fedotov},
title = {Low-temperature synthesis in the dittmarite–sodium acetate trihydrate system: electrochemical activity of M3+/M2+ redox couples in AMPO4 (A = Na, Li; M = Mn, Mn/Fe)},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {mar},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0959943624000853},
number = {2},
pages = {242--245},
doi = {10.1016/j.mencom.2024.02.027}
}
MLA
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Samarin, Aleksandr Sh, et al. “Low-temperature synthesis in the dittmarite–sodium acetate trihydrate system: electrochemical activity of M3+/M2+ redox couples in AMPO4 (A = Na, Li; M = Mn, Mn/Fe).” Mendeleev Communications, vol. 34, no. 2, Mar. 2024, pp. 242-245. https://linkinghub.elsevier.com/retrieve/pii/S0959943624000853.