Phenyl substitution as an effective way to control the luminescent properties of polyphenylcyclopentadienyl lanthanide complexes
Lada N. Puntus
1, 2
,
Daniil A. Bardonov
1, 3
,
Evgeniya A Varaksina
1, 4
,
Ilya V. Taydakov
1, 4
,
Dmitrii M. Roitershtein
1, 5
,
Ilya E. Nifant'ev
1, 6
,
4
6
Publication type: Journal Article
Publication date: 2024-05-27
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
Abstract
Lanthanide complexes [CpXLnCl2(Me3tach)]n (Ln = Tb, Gd; CpX = Cp, CpPh2, CpPh4; Me3tach = 1,3,5-trimethyl-1,3,5- triazacyclohexane; n = 1, 2), containing cyclopentadienyl (Cp), 1,3-diphenylcyclopentadienyl (CpPh2) and tetraphenyl- cyclopentadienyl (CpPh4) anions as ν-bonded antenna ligands, have been synthesized. A combined analysis of quantum chemical, optical and X-ray diffraction data has shown that the introduction of phenyl groups into the Cp ring leads to the inevitable appearance of intraligand charge transfer states due to the nonequivalence of the phenyl rings.
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Citations from 2025:
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Puntus L. N. et al. Phenyl substitution as an effective way to control the luminescent properties of polyphenylcyclopentadienyl lanthanide complexes // Mendeleev Communications. 2024. Vol. 34. No. 3. pp. 325-328.
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Puntus L. N., Bardonov D. A., Varaksina E. A., Taydakov I. V., Roitershtein D. M., Nifant'ev I. E., Lyssenko K. A. Phenyl substitution as an effective way to control the luminescent properties of polyphenylcyclopentadienyl lanthanide complexes // Mendeleev Communications. 2024. Vol. 34. No. 3. pp. 325-328.
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TY - JOUR
DO - 10.1016/j.mencom.2024.04.005
UR - https://linkinghub.elsevier.com/retrieve/pii/S095994362400124X
TI - Phenyl substitution as an effective way to control the luminescent properties of polyphenylcyclopentadienyl lanthanide complexes
T2 - Mendeleev Communications
AU - Puntus, Lada N.
AU - Bardonov, Daniil A.
AU - Varaksina, Evgeniya A
AU - Taydakov, Ilya V.
AU - Roitershtein, Dmitrii M.
AU - Nifant'ev, Ilya E.
AU - Lyssenko, Konstantin A.
PY - 2024
DA - 2024/05/27
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 325-328
IS - 3
VL - 34
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2024_Puntus,
author = {Lada N. Puntus and Daniil A. Bardonov and Evgeniya A Varaksina and Ilya V. Taydakov and Dmitrii M. Roitershtein and Ilya E. Nifant'ev and Konstantin A. Lyssenko},
title = {Phenyl substitution as an effective way to control the luminescent properties of polyphenylcyclopentadienyl lanthanide complexes},
journal = {Mendeleev Communications},
year = {2024},
volume = {34},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {may},
url = {https://linkinghub.elsevier.com/retrieve/pii/S095994362400124X},
number = {3},
pages = {325--328},
doi = {10.1016/j.mencom.2024.04.005}
}
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MLA
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Puntus, Lada N., et al. “Phenyl substitution as an effective way to control the luminescent properties of polyphenylcyclopentadienyl lanthanide complexes.” Mendeleev Communications, vol. 34, no. 3, May. 2024, pp. 325-328. https://linkinghub.elsevier.com/retrieve/pii/S095994362400124X.