Microporous and Mesoporous Materials, volume 196, pages 59-67

Measurements of water vapour sorption isotherms for RD silica gel, AQSOA-Z01, AQSOA-Z02, AQSOA-Z05 and CECA zeolite 3A

Publication typeJournal Article
Publication date2014-09-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor5.2
ISSN13871811
General Chemistry
Condensed Matter Physics
General Materials Science
Mechanics of Materials
Abstract
The water vapour adsorption isotherms of RD silica gel, AQSOA-Z01, AQSOA-Z02, AQSOA-Z05 and CECA zeolite 3A are measured for temperatures between 20 °C and 160 °C and vapour partial pressures between 1 and 500 mbar. The measurements were fit to a theoretical isotherm function and for some materials the RMS deviation was less than 5%. Since others had a poorer theoretical fit, all data was also fit to spline functions for use in numerical simulations. The variation of isosteric heats of adsorption as a function of uptake, calculated using a least squares fitting approach, are compared over a range of uptake values for each adsorbent. The heats of adsorption were between 1 and 1.6 times the heat of vaporisation for uptake values above 10% of the maximum uptake for each adsorbent. The AQSOA adsorbents display Type IV isotherm shapes and the silica gel and 3A zeolite display Type I shapes. The sorption hysteresis is investigated for the AQSOA adsorbents at a selected temperature. These adsorbents displayed a small degree of hysteresis with an H1 type behaviour.

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Goldsworthy M. J. Measurements of water vapour sorption isotherms for RD silica gel, AQSOA-Z01, AQSOA-Z02, AQSOA-Z05 and CECA zeolite 3A // Microporous and Mesoporous Materials. 2014. Vol. 196. pp. 59-67.
GOST all authors (up to 50) Copy
Goldsworthy M. J. Measurements of water vapour sorption isotherms for RD silica gel, AQSOA-Z01, AQSOA-Z02, AQSOA-Z05 and CECA zeolite 3A // Microporous and Mesoporous Materials. 2014. Vol. 196. pp. 59-67.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.micromeso.2014.04.046
UR - https://doi.org/10.1016/j.micromeso.2014.04.046
TI - Measurements of water vapour sorption isotherms for RD silica gel, AQSOA-Z01, AQSOA-Z02, AQSOA-Z05 and CECA zeolite 3A
T2 - Microporous and Mesoporous Materials
AU - Goldsworthy, Mark J.
PY - 2014
DA - 2014/09/01 00:00:00
PB - Elsevier
SP - 59-67
VL - 196
SN - 1387-1811
ER -
BibTex
Cite this
BibTex Copy
@article{2014_Goldsworthy,
author = {Mark J. Goldsworthy},
title = {Measurements of water vapour sorption isotherms for RD silica gel, AQSOA-Z01, AQSOA-Z02, AQSOA-Z05 and CECA zeolite 3A},
journal = {Microporous and Mesoporous Materials},
year = {2014},
volume = {196},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.micromeso.2014.04.046},
pages = {59--67},
doi = {10.1016/j.micromeso.2014.04.046}
}
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