Microporous and Mesoporous Materials, volume 196, pages 59-67
Measurements of water vapour sorption isotherms for RD silica gel, AQSOA-Z01, AQSOA-Z02, AQSOA-Z05 and CECA zeolite 3A
Publication type: Journal Article
Publication date: 2014-09-01
Journal:
Microporous and Mesoporous Materials
Q1
Q2
SJR: 0.941
CiteScore: 10.7
Impact factor: 4.8
ISSN: 13871811, 18733093
General Chemistry
Condensed Matter Physics
General Materials Science
Mechanics of Materials
Abstract
The water vapour adsorption isotherms of RD silica gel, AQSOA-Z01, AQSOA-Z02, AQSOA-Z05 and CECA zeolite 3A are measured for temperatures between 20 °C and 160 °C and vapour partial pressures between 1 and 500 mbar. The measurements were fit to a theoretical isotherm function and for some materials the RMS deviation was less than 5%. Since others had a poorer theoretical fit, all data was also fit to spline functions for use in numerical simulations. The variation of isosteric heats of adsorption as a function of uptake, calculated using a least squares fitting approach, are compared over a range of uptake values for each adsorbent. The heats of adsorption were between 1 and 1.6 times the heat of vaporisation for uptake values above 10% of the maximum uptake for each adsorbent. The AQSOA adsorbents display Type IV isotherm shapes and the silica gel and 3A zeolite display Type I shapes. The sorption hysteresis is investigated for the AQSOA adsorbents at a selected temperature. These adsorbents displayed a small degree of hysteresis with an H1 type behaviour.
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Goldsworthy M. J. Measurements of water vapour sorption isotherms for RD silica gel, AQSOA-Z01, AQSOA-Z02, AQSOA-Z05 and CECA zeolite 3A // Microporous and Mesoporous Materials. 2014. Vol. 196. pp. 59-67.
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Goldsworthy M. J. Measurements of water vapour sorption isotherms for RD silica gel, AQSOA-Z01, AQSOA-Z02, AQSOA-Z05 and CECA zeolite 3A // Microporous and Mesoporous Materials. 2014. Vol. 196. pp. 59-67.
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TY - JOUR
DO - 10.1016/j.micromeso.2014.04.046
UR - https://doi.org/10.1016/j.micromeso.2014.04.046
TI - Measurements of water vapour sorption isotherms for RD silica gel, AQSOA-Z01, AQSOA-Z02, AQSOA-Z05 and CECA zeolite 3A
T2 - Microporous and Mesoporous Materials
AU - Goldsworthy, Mark J.
PY - 2014
DA - 2014/09/01
PB - Elsevier
SP - 59-67
VL - 196
SN - 1387-1811
SN - 1873-3093
ER -
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@article{2014_Goldsworthy,
author = {Mark J. Goldsworthy},
title = {Measurements of water vapour sorption isotherms for RD silica gel, AQSOA-Z01, AQSOA-Z02, AQSOA-Z05 and CECA zeolite 3A},
journal = {Microporous and Mesoporous Materials},
year = {2014},
volume = {196},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/j.micromeso.2014.04.046},
pages = {59--67},
doi = {10.1016/j.micromeso.2014.04.046}
}