Microporous and Mesoporous Materials, volume 196, pages 59-67

Measurements of water vapour sorption isotherms for RD silica gel, AQSOA-Z01, AQSOA-Z02, AQSOA-Z05 and CECA zeolite 3A

Mark J. Goldsworthy ¹

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Commonwealth Scientific and Industrial Research Organisation, Newcastle, Australia |

Publication type: Journal Article

Publication date: 2014-09-01

Elsevier

Journal: Microporous and Mesoporous Materials

Quartile SCImago

Quartile WOS

Impact factor: 5.2

ISSN: 13871811

DOI: 10.1016/j.micromeso.2014.04.046

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General Chemistry

Condensed Matter Physics

General Materials Science

Mechanics of Materials

Abstract

The water vapour adsorption isotherms of RD silica gel, AQSOA-Z01, AQSOA-Z02, AQSOA-Z05 and CECA zeolite 3A are measured for temperatures between 20 °C and 160 °C and vapour partial pressures between 1 and 500 mbar. The measurements were fit to a theoretical isotherm function and for some materials the RMS deviation was less than 5%. Since others had a poorer theoretical fit, all data was also fit to spline functions for use in numerical simulations. The variation of isosteric heats of adsorption as a function of uptake, calculated using a least squares fitting approach, are compared over a range of uptake values for each adsorbent. The heats of adsorption were between 1 and 1.6 times the heat of vaporisation for uptake values above 10% of the maximum uptake for each adsorbent. The AQSOA adsorbents display Type IV isotherm shapes and the silica gel and 3A zeolite display Type I shapes. The sorption hysteresis is investigated for the AQSOA adsorbents at a selected temperature. These adsorbents displayed a small degree of hysteresis with an H1 type behaviour.

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Goldsworthy M. J. Measurements of water vapour sorption isotherms for RD silica gel, AQSOA-Z01, AQSOA-Z02, AQSOA-Z05 and CECA zeolite 3A // Microporous and Mesoporous Materials. 2014. Vol. 196. pp. 59-67.

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TY - JOUR

DO - 10.1016/j.micromeso.2014.04.046

UR - https://doi.org/10.1016/j.micromeso.2014.04.046

TI - Measurements of water vapour sorption isotherms for RD silica gel, AQSOA-Z01, AQSOA-Z02, AQSOA-Z05 and CECA zeolite 3A

T2 - Microporous and Mesoporous Materials

AU - Goldsworthy, Mark J.

PY - 2014

DA - 2014/09/01 00:00:00

PB - Elsevier

SP - 59-67

VL - 196

SN - 1387-1811

ER -

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@article{2014_Goldsworthy,

author = {Mark J. Goldsworthy},

title = {Measurements of water vapour sorption isotherms for RD silica gel, AQSOA-Z01, AQSOA-Z02, AQSOA-Z05 and CECA zeolite 3A},

journal = {Microporous and Mesoporous Materials},

year = {2014},

volume = {196},

publisher = {Elsevier},

month = {sep},

url = {https://doi.org/10.1016/j.micromeso.2014.04.046},

pages = {59--67},

doi = {10.1016/j.micromeso.2014.04.046}

}

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Publisher

Elsevier

Journal

Microporous and Mesoporous Materials

Quartile SCImago

Quartile WOS

Impact factor

5.2

ISSN

13871811 (Print)