volume 294 pages 109912

New insight of the influence of acidic surface sites of zeolite on the ability to remove gaseous ozone using operando DRIFTS studies

Publication typeJournal Article
Publication date2020-03-01
scimago Q1
wos Q2
SJR1.003
CiteScore11.0
Impact factor4.7
ISSN13871811, 18733093
General Chemistry
Condensed Matter Physics
General Materials Science
Mechanics of Materials
Abstract
Recently, natural zeolites have started to be used as alternative materials for ozone abatement from working environments. In this study, a surface response methodology based on a D-Optimal design is applied to develop a transition-metal-modified natural zeolite that increases ozone removal efficiency. Ozone adsorption and/or decomposition onto natural and cobalt modified natural zeolite were studied by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). Results evidenced that ozone is adsorbed and decomposed at strong Lewis acidic sites, whereas ozone adsorption products interact with surface OH groups. Additionally, DRIFTS studies indicate that nitrous species are adsorbed at acidic sites, reducing the capacity to decompose ozone when ozone is generated from air.
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GOST Copy
Valdés H. et al. New insight of the influence of acidic surface sites of zeolite on the ability to remove gaseous ozone using operando DRIFTS studies // Microporous and Mesoporous Materials. 2020. Vol. 294. p. 109912.
GOST all authors (up to 50) Copy
Valdés H., Ulloa F. J., Solar V. A., Cepeda M. S., Azzolina Jury F., Thibault-Starzyk F. New insight of the influence of acidic surface sites of zeolite on the ability to remove gaseous ozone using operando DRIFTS studies // Microporous and Mesoporous Materials. 2020. Vol. 294. p. 109912.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.micromeso.2019.109912
UR - https://doi.org/10.1016/j.micromeso.2019.109912
TI - New insight of the influence of acidic surface sites of zeolite on the ability to remove gaseous ozone using operando DRIFTS studies
T2 - Microporous and Mesoporous Materials
AU - Valdés, Héctor
AU - Ulloa, Francisco J
AU - Solar, Víctor A
AU - Cepeda, Manuel S
AU - Azzolina Jury, Federico
AU - Thibault-Starzyk, Frédéric
PY - 2020
DA - 2020/03/01
PB - Elsevier
SP - 109912
VL - 294
SN - 1387-1811
SN - 1873-3093
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Valdés,
author = {Héctor Valdés and Francisco J Ulloa and Víctor A Solar and Manuel S Cepeda and Federico Azzolina Jury and Frédéric Thibault-Starzyk},
title = {New insight of the influence of acidic surface sites of zeolite on the ability to remove gaseous ozone using operando DRIFTS studies},
journal = {Microporous and Mesoporous Materials},
year = {2020},
volume = {294},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/j.micromeso.2019.109912},
pages = {109912},
doi = {10.1016/j.micromeso.2019.109912}
}