Effective formation of ethyl acetate from ethanol over Cu-Zn-Zr-Al-O catalyst
1
2
Chisso Petrochemical Corporation, 5-1 Goi-kaigan, Ichihara 290-8551, Japan
|
Publication type: Journal Article
Publication date: 2004-07-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 13811169
Catalysis
Physical and Theoretical Chemistry
Process Chemistry and Technology
Abstract
Post-treatment of reduced copper catalyst, which contains Zn, Zr, and Al, with alkaline solution is effective in improving the selectivity to ethyl acetate in the dehydrogenative dimerization of ethanol. The treatment with Na2CO3 and K2CO3 greatly suppressed the formation of by-products such as butanone and 2-butanol, and resulted in the improvement of the selectivity to ethyl acetate. The suppression of butanone and 2-butanol is caused by the neutralization of surface acid sites that are active for the dehydration from 1,3-butanediol, into which acetaldol is hydrogenated. These acid-sites are formed after reduction of the Cu-Zn-Zr-Al-O mixed oxide precursor, and thus the post-treatment is effective. We also discuss the reaction routes in the side reactions.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
2
4
6
8
10
12
|
|
|
Applied Catalysis A: General
11 publications, 9.73%
|
|
|
Journal of Catalysis
6 publications, 5.31%
|
|
|
Industrial & Engineering Chemistry Research
5 publications, 4.42%
|
|
|
Journal of Molecular Catalysis A Chemical
4 publications, 3.54%
|
|
|
Green Chemistry
4 publications, 3.54%
|
|
|
Reaction Kinetics, Mechanisms and Catalysis
3 publications, 2.65%
|
|
|
Journal of Industrial and Engineering Chemistry
3 publications, 2.65%
|
|
|
International Journal of Hydrogen Energy
3 publications, 2.65%
|
|
|
Chemical Engineering Journal
3 publications, 2.65%
|
|
|
ChemCatChem
3 publications, 2.65%
|
|
|
ACS Sustainable Chemistry and Engineering
3 publications, 2.65%
|
|
|
Catalysts
2 publications, 1.77%
|
|
|
Biomass Conversion and Biorefinery
2 publications, 1.77%
|
|
|
Topics in Catalysis
2 publications, 1.77%
|
|
|
Applied Catalysis B: Environmental
2 publications, 1.77%
|
|
|
Catalysis Communications
2 publications, 1.77%
|
|
|
Catalysis Today
2 publications, 1.77%
|
|
|
ChemistrySelect
2 publications, 1.77%
|
|
|
ACS Catalysis
2 publications, 1.77%
|
|
|
Journal of Physical Chemistry Letters
2 publications, 1.77%
|
|
|
Processes
1 publication, 0.88%
|
|
|
Progress in Reaction Kinetics and Mechanism
1 publication, 0.88%
|
|
|
Journal of Sol-Gel Science and Technology
1 publication, 0.88%
|
|
|
Chemical Research in Chinese Universities
1 publication, 0.88%
|
|
|
Brazilian Journal of Chemical Engineering
1 publication, 0.88%
|
|
|
Journal of Chemical Sciences
1 publication, 0.88%
|
|
|
Chemistry Central Journal
1 publication, 0.88%
|
|
|
Biotechnology for Biofuels
1 publication, 0.88%
|
|
|
Resources Chemicals and Materials
1 publication, 0.88%
|
|
|
2
4
6
8
10
12
|
Publishers
|
10
20
30
40
50
60
|
|
|
Elsevier
51 publications, 45.13%
|
|
|
American Chemical Society (ACS)
15 publications, 13.27%
|
|
|
Springer Nature
12 publications, 10.62%
|
|
|
Wiley
11 publications, 9.73%
|
|
|
Royal Society of Chemistry (RSC)
8 publications, 7.08%
|
|
|
MDPI
3 publications, 2.65%
|
|
|
Korean Society of Industrial Engineering Chemistry
3 publications, 2.65%
|
|
|
SAGE
1 publication, 0.88%
|
|
|
Brazilian Society of Chemical Engineering
1 publication, 0.88%
|
|
|
IOP Publishing
1 publication, 0.88%
|
|
|
Pleiades Publishing
1 publication, 0.88%
|
|
|
European Journal of Chemistry
1 publication, 0.88%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 0.88%
|
|
|
10
20
30
40
50
60
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
113
Total citations:
113
Citations from 2025:
7
(6.19%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Inui K. et al. Effective formation of ethyl acetate from ethanol over Cu-Zn-Zr-Al-O catalyst // Journal of Molecular Catalysis A Chemical. 2004. Vol. 216. No. 1. pp. 147-156.
GOST all authors (up to 50)
Copy
Inui K., Kurabayashi T., Sato S., Ichikawa N. Effective formation of ethyl acetate from ethanol over Cu-Zn-Zr-Al-O catalyst // Journal of Molecular Catalysis A Chemical. 2004. Vol. 216. No. 1. pp. 147-156.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.molcata.2004.02.017
UR - https://doi.org/10.1016/j.molcata.2004.02.017
TI - Effective formation of ethyl acetate from ethanol over Cu-Zn-Zr-Al-O catalyst
T2 - Journal of Molecular Catalysis A Chemical
AU - Inui, Kanichiro
AU - Kurabayashi, Toru
AU - Sato, Satoshi
AU - Ichikawa, Naoki
PY - 2004
DA - 2004/07/01
PB - Elsevier
SP - 147-156
IS - 1
VL - 216
SN - 1381-1169
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2004_Inui,
author = {Kanichiro Inui and Toru Kurabayashi and Satoshi Sato and Naoki Ichikawa},
title = {Effective formation of ethyl acetate from ethanol over Cu-Zn-Zr-Al-O catalyst},
journal = {Journal of Molecular Catalysis A Chemical},
year = {2004},
volume = {216},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.molcata.2004.02.017},
number = {1},
pages = {147--156},
doi = {10.1016/j.molcata.2004.02.017}
}
Cite this
MLA
Copy
Inui, Kanichiro, et al. “Effective formation of ethyl acetate from ethanol over Cu-Zn-Zr-Al-O catalyst.” Journal of Molecular Catalysis A Chemical, vol. 216, no. 1, Jul. 2004, pp. 147-156. https://doi.org/10.1016/j.molcata.2004.02.017.