Effective formation of ethyl acetate from ethanol over Cu-Zn-Zr-Al-O catalyst
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Chisso Petrochemical Corporation, 5-1 Goi-kaigan, Ichihara 290-8551, Japan
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Тип публикации: Journal Article
Дата публикации: 2004-07-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 13811169
Catalysis
Physical and Theoretical Chemistry
Process Chemistry and Technology
Краткое описание
Post-treatment of reduced copper catalyst, which contains Zn, Zr, and Al, with alkaline solution is effective in improving the selectivity to ethyl acetate in the dehydrogenative dimerization of ethanol. The treatment with Na2CO3 and K2CO3 greatly suppressed the formation of by-products such as butanone and 2-butanol, and resulted in the improvement of the selectivity to ethyl acetate. The suppression of butanone and 2-butanol is caused by the neutralization of surface acid sites that are active for the dehydration from 1,3-butanediol, into which acetaldol is hydrogenated. These acid-sites are formed after reduction of the Cu-Zn-Zr-Al-O mixed oxide precursor, and thus the post-treatment is effective. We also discuss the reaction routes in the side reactions.
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Inui K. et al. Effective formation of ethyl acetate from ethanol over Cu-Zn-Zr-Al-O catalyst // Journal of Molecular Catalysis A Chemical. 2004. Vol. 216. No. 1. pp. 147-156.
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Inui K., Kurabayashi T., Sato S., Ichikawa N. Effective formation of ethyl acetate from ethanol over Cu-Zn-Zr-Al-O catalyst // Journal of Molecular Catalysis A Chemical. 2004. Vol. 216. No. 1. pp. 147-156.
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TY - JOUR
DO - 10.1016/j.molcata.2004.02.017
UR - https://doi.org/10.1016/j.molcata.2004.02.017
TI - Effective formation of ethyl acetate from ethanol over Cu-Zn-Zr-Al-O catalyst
T2 - Journal of Molecular Catalysis A Chemical
AU - Inui, Kanichiro
AU - Kurabayashi, Toru
AU - Sato, Satoshi
AU - Ichikawa, Naoki
PY - 2004
DA - 2004/07/01
PB - Elsevier
SP - 147-156
IS - 1
VL - 216
SN - 1381-1169
ER -
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@article{2004_Inui,
author = {Kanichiro Inui and Toru Kurabayashi and Satoshi Sato and Naoki Ichikawa},
title = {Effective formation of ethyl acetate from ethanol over Cu-Zn-Zr-Al-O catalyst},
journal = {Journal of Molecular Catalysis A Chemical},
year = {2004},
volume = {216},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/j.molcata.2004.02.017},
number = {1},
pages = {147--156},
doi = {10.1016/j.molcata.2004.02.017}
}
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Inui, Kanichiro, et al. “Effective formation of ethyl acetate from ethanol over Cu-Zn-Zr-Al-O catalyst.” Journal of Molecular Catalysis A Chemical, vol. 216, no. 1, Jul. 2004, pp. 147-156. https://doi.org/10.1016/j.molcata.2004.02.017.