Comparison of the epoxidation of cyclohexene, dicyclopentadiene and 1,5-cyclooctadiene over LDH hosted Fe and Mn sulfonato-salen complexes
Publication type: Journal Article
Publication date: 2006-04-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 13811169
Catalysis
Physical and Theoretical Chemistry
Process Chemistry and Technology
Abstract
Sulfonato-salen metal complexes containing Fe or Mn metal centres have been synthesised and intercalated into Zn/Al layered double hydroxide hosts and used as catalyst for the epoxidation of cyclohexene, dicyclopentadiene and 1,5-cyclooctadiene. Using a combination of pivalaldehyde and molecular oxygen at atmospheric or higher pressures to produce the corresponding peracid as oxidant, cyclohexene gave two oxidation products, cyclohexene oxide and 2-cyclohexen-1-one, whereas, dicyclopentadiene was transformed exclusively into the corresponding mono-epoxide. The relative order of olefin activity correlates with the C–C C bond angle for both metal centres. The product selectivity was found to be largely independent of the central metal ion suggesting that the local environment around the central metal ion was of greater importance. A possible mechanism-based on the product distribution is suggested.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
5
6
|
|
|
Journal of Molecular Catalysis A Chemical
6 publications, 8.7%
|
|
|
Catalysts
3 publications, 4.35%
|
|
|
Catalysis Letters
3 publications, 4.35%
|
|
|
Applied Clay Science
3 publications, 4.35%
|
|
|
Catalysis Today
2 publications, 2.9%
|
|
|
Inorganica Chimica Acta
2 publications, 2.9%
|
|
|
Microporous and Mesoporous Materials
2 publications, 2.9%
|
|
|
Molecular Catalysis
2 publications, 2.9%
|
|
|
Applied Catalysis A: General
2 publications, 2.9%
|
|
|
Catalysis Communications
2 publications, 2.9%
|
|
|
Chemical Communications
2 publications, 2.9%
|
|
|
RSC Advances
2 publications, 2.9%
|
|
|
Journal of Molecular Structure
2 publications, 2.9%
|
|
|
Journal of Organic Chemistry
1 publication, 1.45%
|
|
|
Journal of Porphyrins and Phthalocyanines
1 publication, 1.45%
|
|
|
Journal of Chemical Research
1 publication, 1.45%
|
|
|
Reaction Kinetics, Mechanisms and Catalysis
1 publication, 1.45%
|
|
|
Journal of Nanoparticle Research
1 publication, 1.45%
|
|
|
Research on Chemical Intermediates
1 publication, 1.45%
|
|
|
Catalysis Surveys from Asia
1 publication, 1.45%
|
|
|
Bulletin of the Korean Chemical Society
1 publication, 1.45%
|
|
|
Journal of Fuel Chemistry and Technology
1 publication, 1.45%
|
|
|
Coordination Chemistry Reviews
1 publication, 1.45%
|
|
|
Polymer Degradation and Stability
1 publication, 1.45%
|
|
|
Chinese Chemical Letters
1 publication, 1.45%
|
|
|
Applied Surface Science
1 publication, 1.45%
|
|
|
Journal of Controlled Release
1 publication, 1.45%
|
|
|
Polyhedron
1 publication, 1.45%
|
|
|
ChemistrySelect
1 publication, 1.45%
|
|
|
1
2
3
4
5
6
|
Publishers
|
5
10
15
20
25
30
35
|
|
|
Elsevier
31 publications, 44.93%
|
|
|
Springer Nature
7 publications, 10.14%
|
|
|
Wiley
7 publications, 10.14%
|
|
|
Royal Society of Chemistry (RSC)
7 publications, 10.14%
|
|
|
American Chemical Society (ACS)
3 publications, 4.35%
|
|
|
MDPI
3 publications, 4.35%
|
|
|
Scientific Research Publishing
2 publications, 2.9%
|
|
|
World Scientific
1 publication, 1.45%
|
|
|
SAGE
1 publication, 1.45%
|
|
|
Trans Tech Publications
1 publication, 1.45%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 1.45%
|
|
|
5
10
15
20
25
30
35
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
69
Total citations:
69
Citations from 2025:
3
(4.35%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Bhattacharjee S., Anderson J. D. Comparison of the epoxidation of cyclohexene, dicyclopentadiene and 1,5-cyclooctadiene over LDH hosted Fe and Mn sulfonato-salen complexes // Journal of Molecular Catalysis A Chemical. 2006. Vol. 249. No. 1-2. pp. 103-110.
GOST all authors (up to 50)
Copy
Bhattacharjee S., Anderson J. D. Comparison of the epoxidation of cyclohexene, dicyclopentadiene and 1,5-cyclooctadiene over LDH hosted Fe and Mn sulfonato-salen complexes // Journal of Molecular Catalysis A Chemical. 2006. Vol. 249. No. 1-2. pp. 103-110.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.molcata.2005.12.042
UR - https://doi.org/10.1016/j.molcata.2005.12.042
TI - Comparison of the epoxidation of cyclohexene, dicyclopentadiene and 1,5-cyclooctadiene over LDH hosted Fe and Mn sulfonato-salen complexes
T2 - Journal of Molecular Catalysis A Chemical
AU - Bhattacharjee, Samiran
AU - Anderson, James D.
PY - 2006
DA - 2006/04/01
PB - Elsevier
SP - 103-110
IS - 1-2
VL - 249
SN - 1381-1169
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2006_Bhattacharjee,
author = {Samiran Bhattacharjee and James D. Anderson},
title = {Comparison of the epoxidation of cyclohexene, dicyclopentadiene and 1,5-cyclooctadiene over LDH hosted Fe and Mn sulfonato-salen complexes},
journal = {Journal of Molecular Catalysis A Chemical},
year = {2006},
volume = {249},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/j.molcata.2005.12.042},
number = {1-2},
pages = {103--110},
doi = {10.1016/j.molcata.2005.12.042}
}
Cite this
MLA
Copy
Bhattacharjee, Samiran, et al. “Comparison of the epoxidation of cyclohexene, dicyclopentadiene and 1,5-cyclooctadiene over LDH hosted Fe and Mn sulfonato-salen complexes.” Journal of Molecular Catalysis A Chemical, vol. 249, no. 1-2, Apr. 2006, pp. 103-110. https://doi.org/10.1016/j.molcata.2005.12.042.