The energetics of solvation and ion-ion interactions in prospidium chloride aqueous solutions
Publication type: Journal Article
Publication date: 2018-08-01
scimago Q1
wos Q1
SJR: 0.935
CiteScore: 10.5
Impact factor: 5.2
ISSN: 01677322, 18733166
Materials Chemistry
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
Spectroscopy
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Abstract
This paper focuses on the first accurate thermochemical study of hydration and interactions of the well-established cytostatics “Prospidine” (prospidium chloride) in water. Enthalpies of solution of the drug have been determined with the isoperibol solution calorimeter at 298 and 313 K and heat capacities of solid prospidine have been obtained with the NETZSCH DSC calorimeter at 275–355 K. Standard enthalpies and heat capacities of solution, partial molal heat capacities at an infinite dilution as well as enthalpic parameters of solute-solute pair interactions have been computed using the Redlich-Rosenfeld-Meyer-type equation and discussed in terms of solute-solvent and solute-solute interactions in a liquid phase.
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Kustov A. V. et al. The energetics of solvation and ion-ion interactions in prospidium chloride aqueous solutions // Journal of Molecular Liquids. 2018. Vol. 263. pp. 49-52.
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Kustov A. V., Antonova O. A., Smirnova N. L., Kladiev A. A., Kudayarova T. V., Gruzdev M. S., Berezin D. B. The energetics of solvation and ion-ion interactions in prospidium chloride aqueous solutions // Journal of Molecular Liquids. 2018. Vol. 263. pp. 49-52.
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TY - JOUR
DO - 10.1016/j.molliq.2018.04.118
UR - https://doi.org/10.1016/j.molliq.2018.04.118
TI - The energetics of solvation and ion-ion interactions in prospidium chloride aqueous solutions
T2 - Journal of Molecular Liquids
AU - Kustov, A. V.
AU - Antonova, O A
AU - Smirnova, N. L.
AU - Kladiev, A A
AU - Kudayarova, T V
AU - Gruzdev, M S
AU - Berezin, D B
PY - 2018
DA - 2018/08/01
PB - Elsevier
SP - 49-52
VL - 263
SN - 0167-7322
SN - 1873-3166
ER -
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@article{2018_Kustov,
author = {A. V. Kustov and O A Antonova and N. L. Smirnova and A A Kladiev and T V Kudayarova and M S Gruzdev and D B Berezin},
title = {The energetics of solvation and ion-ion interactions in prospidium chloride aqueous solutions},
journal = {Journal of Molecular Liquids},
year = {2018},
volume = {263},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/j.molliq.2018.04.118},
pages = {49--52},
doi = {10.1016/j.molliq.2018.04.118}
}