Carbamate-bearing surfactants: Micellization, solubilization, and biological activity
Publication type: Journal Article
Publication date: 2018-11-01
scimago Q1
wos Q1
SJR: 0.935
CiteScore: 10.5
Impact factor: 5.2
ISSN: 01677322, 18733166
Materials Chemistry
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
Spectroscopy
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Abstract
Herein novel cationic carbamate-bearing surfactants have been synthesized and characterized as effective building blocks for the development of polyfunctional nanosystems showing solubilizing, antimicrobial and membrane-tropic activity. For this purpose aggregation behavior of the surfactants has been evaluated, with the structure of head group and hydrophobicity varied. Their concentration and temperature ranges of micelle formation have been determined through tensiometry and conductometry: critical micelle concentration, Krafft point and adsorption parameters at the interface have been quantified. Solubilization of hydrophobic probes (Orange OT and pyrene) has been employed to determine aggregation numbers, evaluate solubilization capacity of micelles, and characterize micropolarity in the localization site of the probe. The value of LD50 of the carbamate-bearing surfactants has been determined (mice, intraperitoneal administration). It has been shown that the surfactants can be related to the class of moderately toxic compounds. Investigation of antimicrobial properties of carbamate-bearing surfactants has determined their significant antibacterial and antifungal activity against Staphylococcus aureus, Escherichia coli, Bacillus cereus, Trichophyton mentagrophytes, and Candida albicans.
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Total citations:
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Citations from 2025:
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(15.38%)
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GOST
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Mirgorodskaya A. B. et al. Carbamate-bearing surfactants: Micellization, solubilization, and biological activity // Journal of Molecular Liquids. 2018. Vol. 269. pp. 203-210.
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Mirgorodskaya A. B., Kushnazarova R. A., Lukashenko S. S., Voloshina A. D., Lenina O. A., Zakharova L. Ya., Sinyashin O. G. Carbamate-bearing surfactants: Micellization, solubilization, and biological activity // Journal of Molecular Liquids. 2018. Vol. 269. pp. 203-210.
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RIS
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TY - JOUR
DO - 10.1016/j.molliq.2018.08.007
UR - https://doi.org/10.1016/j.molliq.2018.08.007
TI - Carbamate-bearing surfactants: Micellization, solubilization, and biological activity
T2 - Journal of Molecular Liquids
AU - Mirgorodskaya, Alla B.
AU - Kushnazarova, Rushana A
AU - Lukashenko, Svetlana S
AU - Voloshina, A. D.
AU - Lenina, Oxana A
AU - Zakharova, Lucia Ya
AU - Sinyashin, Oleg G.
PY - 2018
DA - 2018/11/01
PB - Elsevier
SP - 203-210
VL - 269
SN - 0167-7322
SN - 1873-3166
ER -
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@article{2018_Mirgorodskaya,
author = {Alla B. Mirgorodskaya and Rushana A Kushnazarova and Svetlana S Lukashenko and A. D. Voloshina and Oxana A Lenina and Lucia Ya Zakharova and Oleg G. Sinyashin},
title = {Carbamate-bearing surfactants: Micellization, solubilization, and biological activity},
journal = {Journal of Molecular Liquids},
year = {2018},
volume = {269},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/j.molliq.2018.08.007},
pages = {203--210},
doi = {10.1016/j.molliq.2018.08.007}
}