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Journal of Molecular Liquids, volume 283, pages 825-833

Spatial structure, thermodynamics and kinetics of formation of hydrazones derived from pyridoxal 5′-phosphate and 2-furoic, thiophene-2-carboxylic hydrazides in solution

Gamov G A ¹

Khodov I A

Belov K. V. ^{2, 3}

Zavalishin M N

Kiselev A N

Usacheva T R ¹

Sharnin V. A.

Khodov Ilya A. ^{3, 4}

Zavalishin Maksim N ¹

Kiselev A N ³

Sharnin V A ¹

Hide authors affiliations Show authors affiliations: 4 affiliations

Research Institute of Thermodynamics and Kinetics of Chemical Processes, Ivanovo State University of Chemistry and Technology, 153000 Ivanovo, Sheremetevskii pr. 7, Russian Federation |

Department of Inorganic and Analytic Chemistry, Ivanovo State University, 153025 Ivanovo, Yermak str., 39. Ivanovo, Russian Federation |

G.A. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, 153045 Ivanovo, Akademicheskaya str. 1, Russian Federation |

⁴

Kazan Federal University, 420008 Kazan, Kremlyovskaya str. 18, Russian Federation |

Publication type: Journal Article

Publication date: 2019-06-01

Elsevier

Journal: Journal of Molecular Liquids

Quartile SCImago

Quartile WOS

Impact factor: 6

ISSN: 01677322, 18733166

DOI: 10.1016/j.molliq.2019.03.125

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Materials Chemistry

Electronic, Optical and Magnetic Materials

Physical and Theoretical Chemistry

Spectroscopy

Atomic and Molecular Physics, and Optics

Condensed Matter Physics

Abstract

The spatial structure of pyridoxal 5′-phosphate hydrazones of 2-furoic hydrazide; thiophene-2-carboxylic hydrazide in aqueous solution was studied by means of quantum chemical calculations and NOE experiment. The hydrazones could exist as a mixture of different conformers; however, the specific ones could be suggested from experimental and calculated data. The stability constants of hydrazones at pH of 1.9; 6.6; 7.0; 7.4 were determined using UV–Vis spectroscopy. Rate constants of the hydrazone formation and hydrolysis reaction within the range of 6.6–7.4 pH were obtained. Isothermal calorimetric titration was performed in order to determine the change in the free Gibbs energy, enthalpy and entropy of hydrazones formation at pH of 6.6. Hydrazones were synthesized and characterized by means of 1H, 13C, 31P NMR, IR, UV–Vis, fluorescent, MS-spectroscopy as well as DSC and elemental analysis.

By date By citations

Citations by journals

	1 2 3 4 5 6 7 8 9
Journal of Molecular Liquids	Journal of Molecular Liquids, 9, 28.13% Journal of Molecular Liquids 9 publications, 28.13%
Russian Journal of Physical Chemistry B	Russian Journal of Physical Chemistry B, 3, 9.38% Russian Journal of Physical Chemistry B 3 publications, 9.38%
Journal of Molecular Structure	Journal of Molecular Structure, 3, 9.38% Journal of Molecular Structure 3 publications, 9.38%
Pharmaceutics	Pharmaceutics, 2, 6.25% Pharmaceutics 2 publications, 6.25%
Molecules	Molecules, 2, 6.25% Molecules 2 publications, 6.25%
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy	Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 2, 6.25% Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy 2 publications, 6.25%
Russian Journal of Physical Chemistry A	Russian Journal of Physical Chemistry A, 1, 3.13% Russian Journal of Physical Chemistry A 1 publication, 3.13%
Journal of Pharmaceutical Sciences	Journal of Pharmaceutical Sciences, 1, 3.13% Journal of Pharmaceutical Sciences 1 publication, 3.13%
Materials	Materials, 1, 3.13% Materials 1 publication, 3.13%
Journal of Photochemistry and Photobiology A: Chemistry	Journal of Photochemistry and Photobiology A: Chemistry, 1, 3.13% Journal of Photochemistry and Photobiology A: Chemistry 1 publication, 3.13%
European Journal of Organic Chemistry	European Journal of Organic Chemistry, 1, 3.13% European Journal of Organic Chemistry 1 publication, 3.13%
International Journal of Chemical Kinetics	International Journal of Chemical Kinetics, 1, 3.13% International Journal of Chemical Kinetics 1 publication, 3.13%
Russian Journal of Inorganic Chemistry	Russian Journal of Inorganic Chemistry, 1, 3.13% Russian Journal of Inorganic Chemistry 1 publication, 3.13%
Dyes and Pigments	Dyes and Pigments, 1, 3.13% Dyes and Pigments 1 publication, 3.13%
Izvestiya Vysshikh Uchebnykh Zavedenii, Seriya Khimiya i Khimicheskaya Tekhnologiya	Izvestiya Vysshikh Uchebnykh Zavedenii, Seriya Khimiya i Khimicheskaya Tekhnologiya, 1, 3.13% Izvestiya Vysshikh Uchebnykh Zavedenii, Seriya Khimiya i Khimicheskaya Tekhnologiya 1 publication, 3.13%
Photochemical and Photobiological Sciences	Photochemical and Photobiological Sciences, 1, 3.13% Photochemical and Photobiological Sciences 1 publication, 3.13%
Results in Chemistry	Results in Chemistry, 1, 3.13% Results in Chemistry 1 publication, 3.13%
	1 2 3 4 5 6 7 8 9

Citations by publishers

	2 4 6 8 10 12 14 16 18
Elsevier	Elsevier, 18, 56.25% Elsevier 18 publications, 56.25%
Pleiades Publishing	Pleiades Publishing, 5, 15.63% Pleiades Publishing 5 publications, 15.63%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 5, 15.63% Multidisciplinary Digital Publishing Institute (MDPI) 5 publications, 15.63%
Wiley	Wiley, 2, 6.25% Wiley 2 publications, 6.25%
Ivanovo State University of Chemistry and Technology	Ivanovo State University of Chemistry and Technology, 1, 3.13% Ivanovo State University of Chemistry and Technology 1 publication, 3.13%
Springer Nature	Springer Nature, 1, 3.13% Springer Nature 1 publication, 3.13%
	2 4 6 8 10 12 14 16 18

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Gamov G. A. et al. Spatial structure, thermodynamics and kinetics of formation of hydrazones derived from pyridoxal 5′-phosphate and 2-furoic, thiophene-2-carboxylic hydrazides in solution // Journal of Molecular Liquids. 2019. Vol. 283. pp. 825-833.

GOST all authors (up to 50) Copy

Gamov G. A., Khodov I. A., Belov K. V., Zavalishin M. N., Kiselev A. N., Usacheva T. R., Sharnin V. A., Khodov I. A., Zavalishin M. N., Kiselev A. N., Sharnin V. A. Spatial structure, thermodynamics and kinetics of formation of hydrazones derived from pyridoxal 5′-phosphate and 2-furoic, thiophene-2-carboxylic hydrazides in solution // Journal of Molecular Liquids. 2019. Vol. 283. pp. 825-833.

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RIS Copy

TY - JOUR

DO - 10.1016/j.molliq.2019.03.125

UR - https://doi.org/10.1016%2Fj.molliq.2019.03.125

TI - Spatial structure, thermodynamics and kinetics of formation of hydrazones derived from pyridoxal 5′-phosphate and 2-furoic, thiophene-2-carboxylic hydrazides in solution

T2 - Journal of Molecular Liquids

AU - Gamov, G A

AU - Khodov, I A

AU - Belov, K. V.

AU - Zavalishin, M N

AU - Kiselev, A N

AU - Usacheva, T R

AU - Sharnin, V. A.

AU - Khodov, Ilya A.

AU - Zavalishin, Maksim N

AU - Kiselev, A N

AU - Sharnin, V A

PY - 2019

DA - 2019/06/01 00:00:00

PB - Elsevier

SP - 825-833

VL - 283

SN - 0167-7322

SN - 1873-3166

ER -

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@article{2019_Gamov,

author = {G A Gamov and I A Khodov and K. V. Belov and M N Zavalishin and A N Kiselev and T R Usacheva and V. A. Sharnin and Ilya A. Khodov and Maksim N Zavalishin and A N Kiselev and V A Sharnin},

title = {Spatial structure, thermodynamics and kinetics of formation of hydrazones derived from pyridoxal 5′-phosphate and 2-furoic, thiophene-2-carboxylic hydrazides in solution},

journal = {Journal of Molecular Liquids},

year = {2019},

volume = {283},

publisher = {Elsevier},

month = {jun},

url = {https://doi.org/10.1016%2Fj.molliq.2019.03.125},

pages = {825--833},

doi = {10.1016/j.molliq.2019.03.125}

}

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Publisher

Elsevier

Journal

Journal of Molecular Liquids

Quartile SCImago

Quartile WOS

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ISSN

01677322 (Print)
18733166 (Electronic)

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UNU Fluid Spectrum

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